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Doyle dirhodium catalyst, Rh2(5S-MEPY)4

Synonym(s):

Dirhodium(II)tetrakis[methyl 2-pyrrolidone-5(S)-carboxylate], acetonitrile/2-propanol complex

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About This Item

Empirical Formula (Hill Notation):
C24H32N4O12Rh2
CAS Number:
Molecular Weight:
774.34
UNSPSC Code:
12352103

Application

Chiral catalyst used for highly enantioselective intramolecular cyclopropanations, intermolecular addition reactions, and intramolecular carbon-hydrogen insertion reactions. Also employed in the synthesis of lactones and lactams in high diastereo-, regio-, and enantioselectivities. For a recent review, see Aldrichimica Acta

Other Notes

For research purposes only-Not for Use in Humans or in Human Clinical Trials.
Under Special Agreement with Regis Technologies, Inc.

Legal Information

Sold under license from Regis Technologies, Inc.

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Doyle, M.P.
Aldrichimica Acta, 29, 3-3 (1996)

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