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399949

Sigma-Aldrich

Vanadium(V) oxyfluoride

99%

Synonym(s):

Vanadium(V) oxytrifluoride, Vanadyl trifluoride

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About This Item

Linear Formula:
VOF3
CAS Number:
13709-31-4
Molecular Weight:
123.94
EC Number:
237-250-7
MDL number:
MFCD00042555
UNSPSC Code:
12352302
PubChem Substance ID:
24864853
NACRES:
NA.23

Quality Level

100

assay

99%

form

powder

reaction suitability

reagent type: catalyst
core: vanadium

solubility

H2O: insoluble(lit.)

application(s)

battery manufacturing

SMILES string

F[V](F)(F)=O

InChI

1S/3FH.O.V/h3*1H;;/q;;;;+3/p-3

InChI key

FXGIDXZUDLFPLD-UHFFFAOYSA-K

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pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH032

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKBR0897V
MKBP1305V
MKBG7657V
MKBB9347
06607HH

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Micah J Niphakis et al.
Organic letters, 13(2), 196-199 (2010-12-15)
A highly convergent strategy to prepare phenanthroindolizidines is reported involving three consecutive C-C coupling reactions. This sequence features a novel VOF(3)-mediated aryl-alkene coupling in the final step, which enables regioselective preparation of C5-substituted phenanthroindolizidines for the first time. This strategy
M D Zidan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56(14), 2693-2698 (2001-01-06)
A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI

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