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378712

Sigma-Aldrich

(1S)-(+)-Menthyl chloroformate

optical purity ee: 97% (GLC)

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5 ML
$60.26
25 ML
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About This Item

Empirical Formula (Hill Notation):
C11H19ClO2
CAS Number:
Molecular Weight:
218.72
Beilstein/REAXYS Number:
2414685
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

$60.26

List Price$65.50Save 8%
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Available to ship onApril 24, 2025Details


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form

liquid

Quality Level

optical activity

[α]20/D +83°, c = 1 in chloroform

optical purity

ee: 97% (GLC)

refractive index

n20/D 1.458 (lit.)

bp

108-109 °C/11 mmHg (lit.)

density

1.031 g/mL at 25 °C (lit.)

functional group

chloro

storage temp.

2-8°C

SMILES string

CC(C)[C@H]1CC[C@H](C)C[C@@H]1OC(Cl)=O

InChI

1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m0/s1

InChI key

KIUPCUCGVCGPPA-AEJSXWLSSA-N

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Application

Chiral auxiliary in the asymmetric synthesis of quaternary carbon centers.[1]

pictograms

Skull and crossbonesCorrosion

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Inhalation - Skin Corr. 1B

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Tetrahedron Letters, 26, 5433-5433 (1985)
Mohammad Mehdi Koleini et al.
The journal of physical chemistry. B, 124(1), 224-233 (2019-12-10)
This study aims to elucidate the impact of salinity on the interactions governing the adsorption of polar aromatic oil compounds onto calcite. To this end, molecular dynamics simulations were employed to assess adsorption of a model polar organic molecule (deprotonated

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