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377481

Sigma-Aldrich

Isopropyltriphenylphosphonium iodide

98%

Synonym(s):

(1-Methylethyl)triphenylphosphonium iodide, NSC 140615

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About This Item

Linear Formula:
(CH3)2CHP(C6H5)3I
CAS Number:
Molecular Weight:
432.28
EC Number:
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22

assay

98%

form

solid

reaction suitability

reaction type: C-C Bond Formation

mp

194-197 °C (lit.)

SMILES string

[I-].CC(C)[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C21H22P.HI/c1-18(2)22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-18H,1-2H3;1H/q+1;/p-1

InChI key

HHBXWXJLQYJJBW-UHFFFAOYSA-M

Related Categories

Application

Employed in Wittig and cyclopropanation reactions.
Reactant for:
  • Total synthesis of heliananes
  • Preparation of highly substituted benzene derivatives
  • Synthesis of curcuphenol and elvirol analogs via a retro-aldol reaction as fungicidal agents
  • 4-substituted methoxylbenzoyl-aryl-thiazoles analogues as potent and orally bioavailable anticancer agents
  • Wittig reaction

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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Journal of the Chemical Society. Perkin Transactions 1, 3211-3211 (1992)
Journal of the Chemical Society. Perkin Transactions 1, 31-31 (1993)
Tetrahedron Letters, 34, 2695-2695 (1993)

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