369667
(R)-(−)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride
98%
Synonym(s):
(R)-(−)-MTPA-Cl, Mosher’s acid chloride
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About This Item
Linear Formula:
C6H5C(OCH3)(CF3)COCl
CAS Number:
Molecular Weight:
252.62
Beilstein/REAXYS Number:
3591563
MDL number:
UNSPSC Code:
12000000
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assay
98%
optical purity
ee: 98% (GLC)
refractive index
n20/D 1.47 (lit.)
bp
213-214 °C (lit.)
density
1.35 g/mL at 25 °C (lit.)
SMILES string
CO[C@](C(Cl)=O)(c1ccccc1)C(F)(F)F
InChI
1S/C10H8ClF3O2/c1-16-9(8(11)15,10(12,13)14)7-5-3-2-4-6-7/h2-6H,1H3/t9-/m0/s1
InChI key
PAORVUMOXXAMPL-VIFPVBQESA-N
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Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Other Notes
doi:10.1038/nprot.2007.354
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Thomas R Hoye et al.
Nature protocols, 2(10), 2451-2458 (2007-10-20)
This protocol details the most commonly used nuclear magnetic resonance (NMR)-based method for deducing the configuration of otherwise unknown stereogenic, secondary carbinol (alcohol) centers (R1R2CHOH (or the analogous amines where OH is replaced by NH2)). This 'Mosher ester analysis' relies
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