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325945

Sigma-Aldrich

Terbium(III) nitrate pentahydrate

99.9% trace metals basis

Synonym(s):

Terbium nitrate pentahydrate, Terbium(3+) nitrate pentahydrate

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About This Item

Linear Formula:
Tb(NO3)3 · 5H2O
CAS Number:
57584-27-7
Molecular Weight:
435.02
EC Number:
233-138-7
MDL number:
MFCD00149867
UNSPSC Code:
12352302
PubChem Substance ID:
24859547
NACRES:
NA.23
assay:
99.9% trace metals basis
form:
solid

Quality Level

200

assay

99.9% trace metals basis

form

solid

reaction suitability

reagent type: catalyst
core: terbium

impurities

≤1500.0 ppm Trace Rare Earth Analysis

SMILES string

O.O.O.O.O.[Tb+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.5H2O.Tb/c3*2-1(3)4;;;;;;/h;;;5*1H2;/q3*-1;;;;;;+3

InChI key

YWROXJNVUWBEPC-UHFFFAOYSA-N

General description

Terbium(III) nitrate pentahydrate can be used as a dopant/precursor to prepare luminescent phosphors for various applications such as optical ceramics, white light emitting diodes, and photodynamic therapy.

Application

Terbium(III) nitrate pentahydrate can be used as:
  • A precursor to prepare Ce-doped terbium aluminum garnets by the photo-induced method.
  • A dopant to synthesize emission-tunable luminescent hydroxyapatite probe for bioimaging.
  • A starting material to prepare metal-organic frameworks for green laser applications.

pictograms

Flame over circleExclamation mark
GHS03,GHS07

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW4592
MKCV3322
MKCS8083
0000241870
MKCQ9935

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I Perhaita et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 130, 188-197 (2017-10-06)
A series of novel apatite-based Ca
Eulogio J Llorent-Martínez et al.
Analytical and bioanalytical chemistry, 410(2), 391-398 (2017-11-18)
We propose an alternative approach for the development of analytical methods based on terbium-sensitized luminescence (TSL). TSL is based on the complexation between Tb(III) ions and fluorescent organic compounds that have appropriate functional groups to complex with Tb(III). We report
Reineke, T.M. et al.
Journal of the American Chemical Society, 121, 1651-1651 (1999)
Hassen Touzi et al.
Sensors (Basel, Switzerland), 21(5) (2021-03-07)
Gadolinium is extensively used in pharmaceuticals and is very toxic, so its sensitive detection is mandatory. This work presents the elaboration of a gadolinium chemical sensor based on 2-methylpyridine-substituted cyclam thin films, deposited on gold electrodes, using electrochemical impedance spectroscopy
Poonam et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 152, 304-310 (2015-08-02)
The ternary terbium(III) complexes [Tb(HDAP)3⋅biq], [Tb(HDAP)3⋅dmph] and [Tb(HDAP)3⋅bathophen] were prepared by using methoxy substituted hydroxyketone ligand HDAP (2-hydroxy-4,6-dimethoxyacetophenone) and an ancillary ligand 2,2-biquinoline or 5,6-dimethyl-1,10-phenanthroline or bathophenanthroline respectively. The ligand and synthesized complexes were characterised based on elemental analysis, FT-IR

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