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Sigma-Aldrich

2-Bromo-9-fluorenone

96%

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About This Item

Empirical Formula (Hill Notation):
C13H7BrO
CAS Number:
Molecular Weight:
259.10
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

96%

form

solid

mp

146-148 °C (lit.)

SMILES string

Brc1ccc2-c3ccccc3C(=O)c2c1

InChI

1S/C13H7BrO/c14-8-5-6-10-9-3-1-2-4-11(9)13(15)12(10)7-8/h1-7H

InChI key

MTCARZDHUIEYMB-UHFFFAOYSA-N

Application

2-Bromo-9-fluorenone was used:
  • as end-capping agent for poly(9,9-dialkylfluorene-2,7-diyl) derivatives
  • in preparation of spirobifluorene ligands
  • in synthesis of altitudinal molecular motors which contain functional groups in their rotor part

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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Oxidative stability and its effect on the photoluminescence of poly (fluorene) derivatives: end group effects.
Lee J-I, et al.
Chemistry of Materials, 11(4), 1083-1088 (1999)
Novel iridium complexes as high-efficiency yellow and red phosphorescent light emitters for organic light-emitting diodes.
Yao JH, et al.
Tetrahedron, 64(48), 10814-10820 (2008)
Gábor London et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(32), 10690-10697 (2013-06-21)
We report the synthesis of altitudinal molecular motors that contain functional groups in their rotor part. In an approach to achieve dynamic control over the properties of solid surfaces, a hydrophobic perfluorobutyl chain and a relatively hydrophilic cyano group were
Guang-Wei Zhang et al.
International journal of molecular sciences, 14(11), 22368-22379 (2013-11-16)
Supramolecular luminescence stems from non-covalent exciton behaviors of active π-segments in supramolecular entities or aggregates via intermolecular forces. Herein, a π-conjugated oligofluorenol, containing self-complementary double hydrogen bonds, was synthesized using Suzuki coupling as a supramolecular semiconductor. Terfluorenol-based random supramolecular polymers

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