298883

(S)-(−)-4-Isopropyl-2-oxazolidinone

99%

• Empirical Formula (Hill Notation): C₆H₁₁NO₂
• CAS Number: 17016-83-0
• Molecular Weight: 129.16
• Beilstein/REAXYS Number: 3588198
• MDL number: MFCD00010847
• UNSPSC Code: 12352005
• PubChem Substance ID: 24858002
• NACRES: NA.22

Properties

• assay: 99%
• form: solid
• optical activity: [α]20/D −18°, c = 6 in ethanol
• optical purity: ee: 98% (GLC)
• mp: 70-73 °C (lit.)
• SMILES string: CC(C)[C@H]1COC(=O)N1
• InChI: 1S/C6H11NO2/c1-4(2)5-3-9-6(8)7-5/h4-5H,3H2,1-2H3,(H,7,8)/t5-/m1/s1
• InChI key: YBUPWRYTXGAWJX-RXMQYKEDSA-N

Description

Application

Reagent employed as a chiral ligand in dirhodium(II) complexes and as a chiral auxiliary in aldol addition reactions. Versatile chiral auxiliary for asymmetric synthesis. For a recent review, see Aldrichimica Acta.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)