288403

trans-Dichlorobis(triphenylphosphine)platinum(II)

• Synonym(s): trans-Bis(triphenylphosphine)platinum dichloride
• Linear Formula: [(C₆H₅)₃P]₂PtCl₂
• CAS Number: 14056-88-3
• Molecular Weight: 790.56
• MDL number: MFCD00010825
• UNSPSC Code: 12161600
• PubChem Substance ID: 24857337
• NACRES: NA.22

Properties

• reaction suitability: core: platinum; reagent type: catalyst
• SMILES string: Cl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChI key: XAFJSPPHVXDRIE-UHFFFAOYSA-L

Description

Application

Catalyst for:

• Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups
• Alkynylation and hydrogenation reactions
• Hetero-Diels-Alder/ring-opening reactions
• Insertion of carbenes into O-H bonds of alcohols
• Cyclopropanation of olefins
• Hydroformylation reactions

Safety Information

• pictograms: GHS08,GHS07
• signalword: Danger
• hcodes: H302,H315,H317,H319,H334,H335,H373
• pcodes: P260 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 3
• target_organs: Central nervous system,Peripheral nervous system, Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves