275956
Methyl p-tolyl sulfide
99%
Synonym(s):
4-(Methylthio)toluene
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assay
99%
form
liquid
refractive index
n20/D 1.573 (lit.)
bp
52-54 °C/1 mmHg (lit.)
density
1.027 g/mL at 25 °C (lit.)
SMILES string
CSc1ccc(C)cc1
InChI
1S/C8H10S/c1-7-3-5-8(9-2)6-4-7/h3-6H,1-2H3
InChI key
VHILIAIEEYLJNA-UHFFFAOYSA-N
Related Categories
General description
Aerobic oxidation of methyl p-tolyl sulfide catalyzed by a heteroscorpionate Ru(II)-aqua complex has been reported. Chloroperoxidase catalyzed oxidation of methyl p-tolyl sulfide has been reported.
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Journal of the American Chemical Society, 125(2), 308-309 (2003-01-09)
fac-[RuII(Cl)(dpp)(L3)]+ (L3 = tris(pyrid-2-yl)methoxymethane (tpmm) = [1A]+ and tris(pyrid-2-yl)pentoxymethane (tppm) = [1B]+ and dpp = di(pyrazol-1-yl)propane) rapidly undergo ligand substitution with water to form fac-[RuII(H2O)(dpp)(L3)]2+ (L3 = tpmm = [2A]2+ and tppm = [2B]2+). In the structure of [2A]2+, the
Chloroperoxidase and hydrogen peroxide: An efficient system for enzymatic enantioselective sulfoxidations
Tetrahedron Asymmetry, 3(1), 95-106 (1992)
Frontiers in chemistry, 7, 858-858 (2020-01-11)
In this work, we elaborated heterogeneous catalysts on the basis of the Venturello complex [PO4{WO(O2)2}4]3- (PW4) and nitrogen-free or nitrogen-doped carbon nanotubes (CNTs or N-CNTs) for epoxidation of alkenes and sulfoxidation of thioethers with aqueous hydrogen peroxide. Catalysts PW4/CNTs and
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