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263451

Sigma-Aldrich

1-Bromo-2,6-difluorobenzene

98%

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About This Item

Linear Formula:
BrC6H3F2
CAS Number:
64248-56-2
Molecular Weight:
192.99
EC Number:
264-750-2
MDL number:
MFCD00009894
UNSPSC Code:
12352100
PubChem Substance ID:
24855974
NACRES:
NA.22

assay

98%

refractive index

n20/D 1.51 (lit.)

SMILES string

Fc1cccc(F)c1Br

InChI

1S/C6H3BrF2/c7-6-4(8)2-1-3-5(6)9/h1-3H

InChI key

HRZTZLCMURHWFY-UHFFFAOYSA-N

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General description

Three-component coupling reaction of 1-bromo-2,6-difluorobenzene with benzyne and isocyanides has been reported.

Application

1-Bromo-2,6-difluorobenzene has been used in the synthesis of tris(fluorophenyl)boranes.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

127.4 °F - closed cup

flash_point_c

53 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Three-component coupling of arynes and organic bromides.
Hiroto Yoshida et al.
Angewandte Chemie (International ed. in English), 50(41), 9676-9679 (2011-09-03)
Juan A Nicasio et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(33), 11016-11020 (2013-07-03)
An analysis of the metal-free reduction of electron deficient olefins by frustrated Lewis pairs indicates that the rate-determining step might be either the heterolytic cleavage of H2 to form an -onium borohydride salt, or the subsequent transfer of the hydride
Ji Gwang Yu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(63), 16044-16050 (2017-08-24)
Four dibenzofuran-type host materials substituted with a carbazolylcarbazole moiety were synthesized to investigate the effect of substitution position on the material parameters and device performances of host materials. The carbazolylcarbazole moiety was substituted at the 1-, 2-, 3-, and 4-positions

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