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247650

Sigma-Aldrich

Hexarhodium(0) hexadecacarbonyl

Rh 57-60 % (approx.)

Synonym(s):

Rhodium(0) carbonyl

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1 G
$372.50

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Estimated to ship onMarch 28, 2025

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1 G
$372.50

About This Item

Linear Formula:
Rh6(CO)16
CAS Number:
28407-51-4
Molecular Weight:
1065.59
EC Number:
249-009-3
MDL number:
MFCD00011206
UNSPSC Code:
12161600
PubChem Substance ID:
24854881
NACRES:
NA.22

$372.50

List Price$745.00Save 50%

Estimated to ship onMarch 28, 2025

Request a Bulk Order

composition

Rh, 57-60% (approx.)

Quality Level

100

reaction suitability

core: rhodium
reagent type: catalyst

SMILES string

[Rh].[Rh].[Rh].[Rh].[Rh].[Rh].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/16CO.6Rh/c16*1-2;;;;;;

InChI key

SZQABOJVTZVBHE-UHFFFAOYSA-N

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Application

Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds
Widely used organometallic catalyst. Applications include the hydroformylation of olefins.[1][2]

Pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ9607
MKCR3441
MKCK7018
MKCF5029
MKBT9952V

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Journal of Materials Chemistry, 5, 75-75 (1995)
Journal of the American Ceramic Society. American Ceramic Society, 78, 1179-1179 (1995)
Crotti, C.; Cenini, S.; Rindone, B. et al.
Journal of the Chemical Society. Chemical Communications, 784-784 (1986)
Murahashi, S.; Imada, Y.; Hirai, Y.
Bulletin of the Chemical Society of Japan, 62, 2968-2968 (1989)
Ojima, I.; Kato, K.; Okabe, M.; Fuchikami, T.
Journal of the American Chemical Society, 109, 7714-7714 (1987)

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