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243493

Sigma-Aldrich

Zirconium(IV) oxynitrate hydrate

Synonym(s):

Zirconyl nitrate hydrate

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$125.00
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Estimated to ship onMarch 29, 2025


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5 G
$60.80
100 G
$125.00
500 G
$472.00

About This Item

Linear Formula:
ZrO(NO3)2 · xH2O
CAS Number:
Molecular Weight:
231.23 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
form:
powder and chunks

$60.80


Estimated to ship onMarch 29, 2025


Request a Bulk Order

form

powder and chunks

Quality Level

composition

Degree of hydration, ~6

color

white

application(s)

battery manufacturing

SMILES string

O=[Zr++].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.H2O.O.Zr/c2*2-1(3)4;;;/h;;1H2;;/q2*-1;;;+2

InChI key

BGMQNYCWALSARE-UHFFFAOYSA-N

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General description

Zirconium(IV) oxynitrate hydrate is a crystalline zirconium compound that exhibits high solubility in water. It typically comprises amixture of oxide and a slightly hydroxide form.

application

Zirconium(IV) oxynitrate hydrate is used to prepare CeO2-ZrO2 mixed oxide catalyst supports.[1] It may be used as zirconium precursor in the preparation of;
  • Pb(Zr0.50Ti0.50)O3 ferroelectric thin films,[2]
  • silica- and alumina-doped nanocrystalline ceria/zirconia (Ce0.5Zr0.5O2).[3]

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

supp_hazards

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Influence of active metal loading and oxygen mobility on coke-free dry reforming of Ni-Co bimetallic catalysts
Djinovic P, et al.
Applied Catalysis. B, Environmental, 125, 259-270 (2012)
Flame-made nanocrystalline ceria/zirconia doped with alumina or silica: structural properties and enhanced oxygen exchange capacity
Schulz H, et al.
Journal of Materials Chemistry, 13(12), 2979-2984 (2003)
Sol-Gel Preparation of Pb (Zr0. 50Ti0. 50) O3 Ferroelectric Thin Films Using Zirconium Oxynitrate as the Zirconium Source
Zeng J, et al.
Journal of the American Ceramic Society. American Ceramic Society, 82(2), 461-464 (1999)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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