Skip to Content
MilliporeSigma
All Photos(1)

Documents

237582

Sigma-Aldrich

Methyl 2-phenylsulfinylacetate

98%

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
C6H5S(O)CH2CO2CH3
CAS Number:
Molecular Weight:
198.24
Beilstein/REAXYS Number:
1953383
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

98%

form

solid

bp

130-131 °C/0.5 mmHg (lit.)

mp

52-54 °C (lit.)

SMILES string

COC(=O)CS(=O)c1ccccc1

InChI

1S/C9H10O3S/c1-12-9(10)7-13(11)8-5-3-2-4-6-8/h2-6H,7H2,1H3

InChI key

JPPXZUDQIXZLIL-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

application

Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Journal of the Chemical Society. Perkin Transactions 1, 2683-2683 (1991)
New Synthetic reactions. Alkylative elimination.
Trost BM, et al.
Journal of the American Chemical Society, 96(22), 7165-7167 (1974)
Phase-Transfer Catalyzed Alkylative Elimination of Methyl 2-Phenylsulfinylacetate. A One-Pot Synthesis of Substituted Cinnamates.
Chong-ying X, et al.
Synthetic Communications, 17(15), 1839-1843 (1987)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service