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Sigma-Aldrich

Sulfur

99.998% trace metals basis

Synonym(s):

sulfur powder

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$47.20
50 G
$134.00
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$499.00

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10 G
$47.20
50 G
$134.00
250 G
$499.00

About This Item

Empirical Formula (Hill Notation):
S
CAS Number:
7704-34-9
Molecular Weight:
32.07
EC Number:
231-722-6
MDL number:
MFCD00085316
UNSPSC Code:
12141912
PubChem Substance ID:
24852677
NACRES:
NA.23
assay:
99.998% trace metals basis
form:
powder or flakes

$47.20

In StockDetails

Request a Bulk Order

vapor density

8.9 (vs air)

Quality Level

200

vapor pressure

1 mmHg ( 183.8 °C)
10 mmHg ( 246 °C)

assay

99.998% trace metals basis

form

powder or flakes

autoignition temp.

450 °F

resistivity

2E23 μΩ-cm, 20°C

bp

444.7 °C (lit.)

mp

112.8 °C (rhombic) (lit.)
117-120 °C (lit.)
119.0 °C (monoclinic) (lit.)

density

2.07 g/mL at 25 °C

SMILES string

[S]

InChI

1S/S

InChI key

NINIDFKCEFEMDL-UHFFFAOYSA-N

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General description

Elemental sulfur exists in thirty different solid allotropes of which orthorhombic sulfur is the only thermodynamically stable form under normal temperature and pressure. It dissolves in a number of organic solvents and forms a large number of oxyacids. Sulfur is generally highly reactive; the S8 ring of elemental sulfur is easily broken by a number of nucleophilic reactants. The hydroxyl ions react with S at about 100oC.

Application

It finds applications in Li-S polymer batteries[1][2] and as semiconductor-sensitizer layer CdS/CdSe/ZnS for solar cells.[3]

Pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315

Hazard Classifications

Skin Irrit. 2

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS1210
MKCP2096
MKCJ0986
MKCJ2975
MKCH2485

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Effects of Nanosized Adsorbing Material on Electrochemical Properties of Sulfur Cathodes for LiOS Secondary Batteries
Journal of the Electrochemical Society, 151(6), A791-A795 (2004)
Preparation and electrochemical properties of lithium-sulfur polymer batteries
Journal of Power Sources, 109(1), 89-97 (2002)
Multilayered semiconductor (CdS/CdSe/ZnS)-sensitized TiO2 mesoporous solar cells: all prepared by successive ionic layer adsorption and reaction processes.
Chemistry of Materials, 22(19), 5636-5643 (2010)
Lingli Huang et al.
Science advances, 6(47) (2020-11-20)
Low-dimensional materials usually exhibit mechanical properties from those of their bulk counterparts. Here, we show in two-dimensional (2D) rhenium disulfide (ReS2) that the fracture processes are dominated by a variety of previously unidentified phenomena, which are not present in bulk
Gulluzar Bastug et al.
The Journal of organic chemistry, 78(18), 9303-9308 (2013-08-14)
The newly prepared complex [Pd(IPr*(OMe))(cin)(Cl)] provides high catalytic activity for carbon-sulfur cross-coupling reactions. Nonactivated and deactivated aryl halides were successfully coupled with a large variety of aryl- and alkylthiols using this well-defined palladium N-heterocyclic carbene (NHC) complex.
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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