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201138

Sigma-Aldrich

Ammonium hexafluorophosphate

≥95%

Synonym(s):

Ammonium hexafluophosphate, Ammonium hexafluorophosphate V, Ammonium phosphorus hexafluoride, Ammoniumhexafluorophosphate

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About This Item

Linear Formula:
NH4PF6
CAS Number:
16941-11-0
Molecular Weight:
163.00
EC Number:
241-009-1
MDL number:
MFCD00064642
UNSPSC Code:
12352302
eCl@ss:
38070413
PubChem Substance ID:
24851996
NACRES:
NA.22

Quality Level

100

assay

≥95%

form

solid

density

2.18 g/mL at 25 °C (lit.)

SMILES string

[H][N+]([H])([H])[H].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1

InChI key

NIZXKAYXSNUDOU-UHFFFAOYSA-O

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Application

Ammonium hexafluorophosphate (NH4PF6) can be used as a precursor for the preparation of:
  • Metal complexes, particularly iridium and rhodium complexes.       
  • Flame retardant cellulose-based materials.       
  • Cyclic amidinium and iminium ammonium hexafluorophosphate salts.        
  • The polymer-supported iridium isomerization catalyst for the selective trans isomerization of aryl allylic derivatives.

Pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Preparations of iridium complexes containing phenanthroline ancillary ligands and electrical properties of cationic iridium-based light-emitting electrochemical cells
Park S, et al.
Surface and Interface Analysis : SIA, 44(11-12), 1479-1482 (2012)
A polymer-supported iridium catalyst for the stereoselective isomerisation of double bonds
Baxendale IR, et al.
Synlett, 2002(03), 0516-0518 (2002)
A simple and efficient one-step protocol for the preparation of alkyl-substituted ammonium tetrafluoroborate and hexafluorophosphate salts
Saba Shahrokh, et al.
Journal of Fluorine Chemistry, 153, 168-171 (2013)
Accelerated luminophore discovery through combinatorial synthesis.
Lowry, Michael S et al.
Journal of the American Chemical Society, 126(43), 14129-14135 (2004)
Homogeneous catalytic system for photoinduced hydrogen production utilizing iridium and rhodium complexes.
Cline, Eric D et al.
Inorganic Chemistry, 47(22), 10378-10388 (2008)
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