s-BuLi when titrated came to about 0.73 M not the 1.4 M stated on the bottle
195596
sec-Butyllithium solution
sec-Butyllithium solution
1 of 3 reviewers received a sample product or took part in a promotion
1.4 M in cyclohexane
Synonym(s):
Lithium-2-butanide, s-BuLi
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50 ML
$57.70
4 X 25 ML
$88.80
100 ML
$93.30
800 ML
$267.00
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50 ML
$57.70
4 X 25 ML
$88.80
100 ML
$93.30
800 ML
$267.00
About This Item
Linear Formula:
CH3CH2CH(CH3)Li
CAS Number:
Molecular Weight:
64.06
Beilstein/REAXYS Number:
3587206
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
concentration:
1.4 M in cyclohexane
Recommended Products
form
liquid
Quality Level
concentration
1.4 M in cyclohexane
density
0.769 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
[Li]C(C)CC
InChI
1S/C4H9.Li/c1-3-4-2;/h3H,4H2,1-2H3;
InChI key
VATDYQWILMGLEW-UHFFFAOYSA-N
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Application
sec-Butyllithium solution (1.4M in cyclohexane) has been used in the multi-step synthesis of 5-methyl-5,6-dihydrothymidine (5-MDHT) from thymidine.[1] It has also been used in the copper-catalyzed asymmetric allylic alkylation (AAA) of allyl bromides, chlorides, and ethers in the presence of a chiral ligand.[2]
Packaging
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Central nervous system
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk_germany
WGK 2
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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