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195332

Sigma-Aldrich

1-Bromotetradecane

97%

Synonym(s):

Myristyl bromide, Tetradecyl bromide

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5 ML
$19.20
500 ML
$113.00

About This Item

Linear Formula:
CH3(CH2)13Br
CAS Number:
Molecular Weight:
277.28
Beilstein/REAXYS Number:
1742640
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

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Quality Level

assay

97%

form

liquid

refractive index

n20/D 1.460 (lit.)

bp

175-178 °C/20 mmHg (lit.)

mp

5-6 °C (lit.)

density

0.932 g/mL at 25 °C (lit.)

functional group

alkyl halide
bromo

SMILES string

CCCCCCCCCCCCCCBr

InChI

1S/C14H29Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-14H2,1H3

InChI key

KOFZTCSTGIWCQG-UHFFFAOYSA-N

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Application

1-Bromotetradecane was used in the synthesis of:
  • tetradecylferrocene[1]
  • cationic and zwitterionic gemini surfactants[2]
  • metallomesogenic polymers based on bis[η1(N)-3,4-dialkyloxybenzylidene-4′-dodecyloxyaniline]dichloropalladium(II) with octyl, decyl, dodecyl, tetradecyl and hexadecyl alkyl groups[3]
  • 9-tetradecylcarbazole[4]

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Novel Metallomesogenic Polymers Derived from ? 1-Benzylideneaniline Palladium (II) Complex.
Lee M, et al.
Macromolecules, 32(8), 2777-2782 (1999)
R Hernández-Bravo et al.
The journal of physical chemistry. B, 122(15), 4325-4335 (2018-03-29)
A combined study for understanding the molecular interactions of asphaltenes with molecular species such as ionic liquids (ILs) comprised experimental measurements and computational numerical simulation calculations, using density-functional theory (DFT) with dispersion corrections, molecular dynamics (MD) calculations, and experimental rheological
Atakilt Abebe et al.
Bioinorganic chemistry and applications, 2018, 8097483-8097483 (2018-08-18)
New organic salts were synthesized by quaternizing 1,10-phenanthroline using 1-bromotetradecane. The first step yielded an organic salt of formula [C26H37N2]Br. Anion exchange reaction using Li[(CF3SO2)2N] resulted in a more stable salt of formula [C26H37N2][(CF3SO2)2N]. The organic salts were investigated by
Nusrat Jahan et al.
The Journal of organic chemistry, 74(20), 7762-7773 (2009-09-18)
Simple strategies for the synthesis of five series of cationic gemini surfactants and one series of zwitterionic gemini surfactants from pentaerythritol have been developed. Two lipophilic groups were introduced onto pentaerythritol by alkylation of the known compound, O-benzylidenepentaerythritol, with 1-bromooctane
Katrin Wedeking et al.
Langmuir : the ACS journal of surfaces and colloids, 22(7), 3161-3165 (2006-03-22)
Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was analyzed by

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