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16494

Sigma-Aldrich

3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexanethiol

≥97.0% (GC)

Synonym(s):

1H,1H,2H,2H-Perfluoro-1-hexanethiol, 3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexyl mercaptan

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About This Item

Empirical Formula (Hill Notation):
C6H5F9S
CAS Number:
Molecular Weight:
280.15
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

assay

≥97.0% (GC)

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)CCS

InChI

1S/C6H5F9S/c7-3(8,1-2-16)4(9,10)5(11,12)6(13,14)15/h16H,1-2H2

InChI key

GQJXVHYUQPXZOL-UHFFFAOYSA-N

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General description

3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexanethiol (PHFT) is a fluorinated thiol which has short fluorinated chains. PHFT is used as a self-assembled monolayer (SAM) for the surface modification of a wide range of nanoparticles.

Application

PHFT can be used to tune and modify the surface characteristics of silver nanoparticles (AgNPs) as a self-assembled monolayer (SAM). It is used in the development of nanofibrous polymeric coating by improving the super-hydrophobicity for restricting the growth of bacteria on the surface. It may also be used in the preparation of an anode for polymeric-light emitting diode (PLED) as it increases the minimum thermodynamic work and reduces the barrier potential for hole-injection.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Superhydrophobic surface properties with various nanofibrous structures by electrodeposition of PEDOT polymers with short fluorinated chains and rigid spacers.
Darmanin T and Guittard F
Synthetic Metals, 205, 58-63 (2015)
Long-pulse laser launch and ionization of tailored large neutral silver nanoparticles with atomic mass assignment.
Gallego A, et al.
Nanoscale, 9(26), 9175-9180 (2017)
Akira Tada et al.
Physical chemistry chemical physics : PCCP, 14(11), 3713-3724 (2012-02-11)
This feature article focuses on the relationship between the interfacial structures constructed by molecular self-organization and the properties of organic photovoltaic devices. The use of self-assembled monolayers (SAMs) is reviewed for metal and metal oxide/organic interfaces, while surface-segregated monolayers (SSMs)
Concomitant tuning of metal work function and wetting property with mixed self-assembled monolayers.
Chen, C. Y., Wu, K. Y., Chao, Y. C., Zan, H. W., Meng, H. F., & Tao, Y. T.
Organic Electronics, 12(1), 148-153 (2011)

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