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160938

Sigma-Aldrich

Resolve-Al EuFOD

99%

Synonym(s):

Eu(fod)3, Europium(III)-tris(1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionate), Sievers’ Reagent, Tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium

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1 G
$77.20
5 G
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About This Item

Linear Formula:
Eu(OCC(CH3)3CHCOCF2CF2CF3)3
CAS Number:
17631-68-4
Molecular Weight:
1037.49
EC Number:
241-616-1
MDL number:
MFCD00064655
UNSPSC Code:
12161600
PubChem Substance ID:
24849895
NACRES:
NA.22

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assay

99%

form

solid

reaction suitability

core: erbium
reagent type: catalyst

mp

203-207 °C

SMILES string

CC(C)(C)C(\O[Eu](O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)O\C(=C/C(=O)C(F)(F)C(F)(F)C(F)(F)F)C(C)(C)C)=C\C(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/3C10H11F7O2.Eu/c3*1-7(2,3)5(18)4-6(19)8(11,12)9(13,14)10(15,16)17;/h3*4,18H,1-3H3;/q;;;+3/p-3/b3*5-4-;

InChI key

PTQJQBFRLLGICD-VNGPFPIXSA-K

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General description

Enhances stereoselectivity in the radical-mediated allylation of oxysuccinate derivatives.

Application

When used in conjunction with Resolve-Al AgFOD, provides an effective NMR shift reagent for aromatic compounds,[1] ammonium salts,[2] and sulfonium and isothiouronium halides.[3]

Legal Information

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
0000221940
0000209682
0000209681
BGBB6126V
BGBC2984V

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A B Ellis et al.
Proceedings of the National Academy of Sciences of the United States of America, 78(7), 3993-3997 (1981-07-01)
Several retinal isomers are shown to form adducts in isooctane solution with a lanthanide beta-diketonate complex, tris(6,6,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato)europium(III) [Eu(fod)3]. The adducts are characterized by an absorption band whose lambda max at approximately 420 nm is red-shifted by approximately 60 nm from
The Journal of Organic Chemistry, 50, 1322-1322 (1985)
Journal of the American Chemical Society, 102, 5903-5903 (1980)
Michiya Fujiki et al.
Frontiers in chemistry, 8, 685-685 (2020-09-10)
We report emerging circularly polarized luminescence (CPL) at 4f-4f transitions when lanthanide (EuIII and TbIII) tris(β-diketonate) embedded to cellulose triacetate (CTA), cellulose acetate butyrate (CABu), D-/L-glucose pentamethyl esters ( D-/ L-Glu), and D-/L-arabinose tetramethyl esters ( D-/ L-Ara) are in
Analytical Chemistry, 59, 562-562 (1987)
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