146552

Benzyltriethylammonium chloride

99%

• Synonym(s): BTEAC
• Linear Formula: C₆H₅CH₂N(Cl)(C₂H₅)₃
• CAS Number: 56-37-1
• Molecular Weight: 227.77
• Beilstein/REAXYS Number: 3574984
• EC Number: 200-270-1
• MDL number: MFCD00011824
• UNSPSC Code: 12352107
• PubChem Substance ID: 24848786
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 99%
• form: solid
• mp: 190-192 °C (dec.) (lit.)
• SMILES string: [Cl-].CC[N+](CC)(CC)Cc1ccccc1
• InChI: 1S/C13H22N.ClH/c1-4-14(5-2,6-3)12-13-10-8-7-9-11-13;/h7-11H,4-6,12H2,1-3H3;1H/q+1;/p-1
• InChI key: HTZCNXWZYVXIMZ-UHFFFAOYSA-M

Description

Application

Benzyltriethylammonium chloride is a lipophilic phase-transfer catalyst that can be used in phase-transfer catalysis (PTC) to catalyze polycondensation reactions to form high molecular weight polymers under bi-phasic conditions.

It can also be used:

• To activate hydroxyapatite and natural phosphate for use as a solid support for Knoevenagel condensation and Claisen-Schmidt condensation, respectively at room temperature and in the absence of a solvent.
• To increase the efficiency of mCPBA oxidation of sulfonimine generated from arenesulfonamide and diethyl acetal of an aromatic aldehyde to form 2-sulfonyloxaziridines.
• In combination with antimony(V) chloride to form a catalytic system for the Friedel-Crafts acylation reactions of arenes with acyl and sulfonyl chlorides.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 1
• flash_point_f: >527.0 °F - closed cup
• flash_point_c: > 275 °C - closed cup
• ppe: dust mask type N95 (US), Eyeshields, Gloves