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Sigma-Aldrich

(Ethoxycarbonylmethyl)dimethylsulfonium bromide

97%

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About This Item

Linear Formula:
C2H5O2CCH2S(CH3)2Br
CAS Number:
5187-82-6
Molecular Weight:
231.15
EC Number:
225-968-3
MDL number:
MFCD00830557
UNSPSC Code:
12352100
PubChem Substance ID:
24848710
NACRES:
NA.22

assay

97%

form

solid

mp

90-94 °C (lit.)

SMILES string

Br.CCOC(=O)C[S](C)C

InChI

1S/C6H13O2S.BrH/c1-4-8-6(7)5-9(2)3;/h4-5H2,1-3H3;1H/q+1;/p-1

InChI key

JXFPTJYKYKVENJ-UHFFFAOYSA-M

Application

(Ethoxycarbonylmethyl)dimethylsulfonium bromide was used in synthesis of α-sulfanyl-β-amino acid derivatives by using nanocrystalline magnesium oxide. It was used during cyclopropanation of (-)-(S)-2-(p-tolylsulfinyl)cyclopent-2-enone.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Constrained cycloalkyl analogues of glutamic acid: stereocontrolled synthesis of (+)-2-aminobicyclo [3.1. 0] hexane-2, 6-dicarboxylic acid (LY354740) and its 6-phosphonic acid analogue
Krysiak J, et al.
Tetrahedron Asymmetry, 21(11), 1486-1493 (2010)
Synthesis of a-sulfanyl-?-amino acid derivatives by using nanocrystalline magnesium oxide.
Kantam ML, et al.
Tetrahedron, 66(27), 5042-5052 (2010)

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