102741
2-Fluorobiphenyl
96%
Synonym(s):
1-Fluoro-2-phenylbenzene, o-Fluorodiphenyl
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About This Item
Linear Formula:
C6H5C6H4F
CAS Number:
Molecular Weight:
172.20
Beilstein/REAXYS Number:
2043175
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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assay
96%
form
solid
bp
248 °C (lit.)
mp
71-74 °C (lit.)
SMILES string
Fc1ccccc1-c2ccccc2
InChI
1S/C12H9F/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9H
InChI key
KLECYOQFQXJYBC-UHFFFAOYSA-N
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General description
2-Fluorobiphenyl is a white to off white powder. It is catabolized by C. elegans, yielding hydroxylated products. The metabolism of 2-fluorobiphenyl by hepatic microsomes isolated from control and aroclor 1254-treated rats and pigeons was studied.
Application
2-Fluorobiphenyl was used as an internal standard for analysis of environmental pollutants in sediments using pressurized liquid extraction and gas chromatography-mass spectrometry. It was used to study the solvent dynamics of 1,2,4,5-tetracyanobenzene/biphenyl derivative radical ion pairs by picosecond absorption spectroscopy. It was also used as a sole carbon and energy source for the biphenyl-degrading bacterium Pseudomonas pseudoalcaligenes KF707.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
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Cormac D Murphy et al.
FEMS microbiology letters, 286(1), 45-49 (2008-07-12)
The biphenyl-degrading bacterium Pseudomonas pseudoalcaligenes KF707 can use 2- and 4-fluorobiphenyl as sole carbon and energy sources. Accumulation of fluorinated catabolites was determined by fluorine-19 nuclear magnetic spectroscopy (19F NMR) and revealed that growth on 4-fluorobiphenyl yielded 4-fluorobenzoate and 4-fluoro-1,2-dihydro-1,2-dihydroxybenzoate
Jessica Amadio et al.
Applied microbiology and biotechnology, 86(1), 345-351 (2009-12-04)
The fungus Cunninghamella elegans is a useful model of human catabolism of xenobiotics. In this paper, the biotransformation of fluorinated biphenyls by C. elegans was investigated by analysis of the culture supernatants with a variety of analytical techniques. 4-Fluorobiphenyl was
Zheng-Xia Chen et al.
Chemosphere, 131, 192-200 (2015-04-12)
Fine roots of woody plants are a heterogeneous system differing markedly in structure and function. Nevertheless, knowledge about the plant uptake of organic pollutants via fine roots is scarce to date. In the present study, plant uptake, translocation, and return
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J T Borlakoglu et al.
Comparative biochemistry and physiology. C, Comparative pharmacology and toxicology, 105(1), 119-125 (1993-05-01)
1. The metabolism of 2-, 3-, 4-bromo-, 2-, 4-chloro-, and 2-fluorobiphenyl by hepatic microsomes isolated from control and Aroclor 1254-treated rats and pigeons was studied. 2. Meta and para as well as dihydroxylated metabolites were detected, but para hydroxylation was
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