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71853

Sigma-Aldrich

Sodium perchlorate monohydrate

puriss. p.a., ACS reagent, ≥98.0% (T)

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About This Item

Linear Formula:
NaClO4 · H2O
CAS Number:
7791-07-3
Molecular Weight:
140.46
EC Number:
231-511-9
MDL number:
MFCD00149164
UNSPSC Code:
12352302
PubChem Substance ID:
329763586
NACRES:
NA.21

grade

ACS reagent
puriss. p.a.

Quality Level

200

assay

≥98.0% (T)

form

powder, crystals or chunks

impurities

≤0.0005% total nitrogen (N)

pH

6.0-8.0 (25 °C, 50 mg/mL in H2O)

anion traces

chloride (Cl-): ≤30 mg/kg
sulfate (SO42-): ≤20 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤3 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

O.[Na+].[O-]Cl(=O)(=O)=O

InChI

1S/ClHO4.Na.H2O/c2-1(3,4)5;;/h(H,2,3,4,5);;1H2/q;+1;/p-1

InChI key

IXGNPUSUVRTQGW-UHFFFAOYSA-M

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General description

Sodium perchlorate monohydrate (NaClO4· H2O) is a hydrated sodium salt. Its crystal structure has been investigated by three-dimensional single crystal x-ray diffraction studies. Its crystals belong to the monoclinic crystal system having space group C2/c.

Application

Sodium perchlorate monohydrate (NaClO4· H2O) may be used in the preparation of 0.01M NaClO4 solution. This solution was employed in oxalate adsorption isotherm experiments.
Sodium perchlorate monohydrate has been used as a component of ion exchange (IE) buffer A and B for the purification of RNA using IE-high-performance liquid chromatography (HPLC).

pictograms

Flame over circleExclamation mark
GHS03,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 1

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Dissolution mechanisms of goethite in the presence of siderophores and organic acids.
Reichard PU, et al.
Geochimica et Cosmochimica Acta, 71(23), 5635-5650 (2007)
Hydrogen bond studies. CII. An X-ray determination of the crystal structure of sodium perchlorate monohydrate, NaClO4. H2O.
Berglund B, et al.
Acta Crystallographica Section B, Structural Science, 31(7), 1842-1846 (1975)
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The aim of this paper is to present a development of liquid chromatographic method when chaotropic salts are used as mobile phase additives following the QbD principles. The effect of critical process parameters (column chemistry, salt nature and concentration, acetonitrile
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