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538973

Sigma-Aldrich

Tris(dibenzoylmethane) mono(5-amino-1,10-phenanthroline)europium (lll)

Synonym(s):

Europium(III) tris(1,3-diphenyl-1,3-propanedionato) mono(5-amino-1,10-phenanthroline)

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About This Item

Empirical Formula (Hill Notation):
C57H45EuN3O6
CAS Number:
Molecular Weight:
1019.95
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

reaction suitability

reagent type: catalyst
core: europium

Quality Level

mp

163-168 °C (lit.)

λmax

244 nm in H2O

SMILES string

Nc1cc2cccnc2c3ncccc13.O=C(\C=C(/O[Eu](O\C(=C\C(=O)c4ccccc4)c5ccccc5)O\C(=C\C(=O)c6ccccc6)c7ccccc7)c8ccccc8)c9ccccc9

InChI

1S/3C15H12O2.C12H9N3.Eu/c3*16-14(12-7-3-1-4-8-12)11-15(17)13-9-5-2-6-10-13;13-10-7-8-3-1-5-14-11(8)12-9(10)4-2-6-15-12;/h3*1-11,16H;1-7H,13H2;/q;;;;+3/p-3/b3*14-11+;;

InChI key

AKNYTGVINNNCMK-RWBKAWJDSA-K

General description

Light emitting metal complex.

Application

Temperature-sensitive europium complexes of tris(dibenzoylmethane) mono(5-amino-1,10-phenanthroline)europium(III) [Eudatp] may be used to fabricate a dual optical sensor to detect oxygen and any change in temperature. This product may be used in the preparation of porphyrin–Eu-β-diketonate supramolecular nanostructures, and in the fabrication of silicon wafers grafted with europium complex.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Dual optical sensor for oxygen and temperature based on the combination of time domain and frequency domain techniques
Hung L, et al.
Talanta, 65-70 null
Optical properties of porphyrin?Eu-?-diketonate supramolecular nanostructures.
Millesi S and Gulino A
Journal of Material Chemistry C null
Optical properties of porphyrin?Eu-?-diketonate supramolecular nanostructures.
Millesi S and Gulino A
Journal of Material Chemistry C, 5924-5930 null
Europium Complex Covalently Grafted on Si (100) Surfaces, Engineered with Covalent Polystyrene Nanostructures.
Cristaldi D, et al.
The Journal of Physical Chemistry C, 16213-16220 null
Europium Complex Covalently Grafted on Si (100) Surfaces, Engineered with Covalent Polystyrene Nanostructures.
Cristaldi D, et al.
The Journal of Physical Chemistry C null

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