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410209

Sigma-Aldrich

L-Cysteine methyl ester hydrochloride

98%, for peptide synthesis

Synonym(s):

(R)-Cysteine methyl ester hydrochloride

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About This Item

Linear Formula:
HSCH2CH(NH2)COOCH3 · HCl
CAS Number:
Molecular Weight:
171.65
Beilstein/REAXYS Number:
3685824
EC Number:
MDL number:
UNSPSC Code:
12352209
eCl@ss:
32160406
PubChem Substance ID:
NACRES:
NA.22

product name

L-Cysteine methyl ester hydrochloride, 98%

assay

98%

form

solid

optical activity

[α]20/D −1.8°, c = 10 in methanol

reaction suitability

reaction type: solution phase peptide synthesis

mp

142 °C (dec.) (lit.)

application(s)

peptide synthesis

SMILES string

Cl[H].COC(=O)[C@@H](N)CS

InChI

1S/C4H9NO2S.ClH/c1-7-4(6)3(5)2-8;/h3,8H,2,5H2,1H3;1H/t3-;/m0./s1

InChI key

WHOHXJZQBJXAKL-DFWYDOINSA-N

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Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Mickael Alimi et al.
Inorganic chemistry, 51(17), 9350-9356 (2012-08-22)
Six Co(III) complexes based on unsubstituted or substituted TPA ligands (where TPA is tris(2-pyridylmethyl)amine) and acetohydroxamic acid (A), N-methyl-acetohydroxamic acid (B), or N-hydroxy-pyridinone (C) were prepared and characterized by mass spectrometry, elemental analysis, and electrochemistry: [Co(III)(TPA)(A-2H)](Cl) (1a), [Co(III)((4-Cl(2))TPA)(A-2H)](Cl) (2a), [Co(III)((6-Piva)TPA)(A-2H)](Cl)
T A Cook et al.
Biochemistry, 39(44), 13516-13523 (2000-11-07)
PDE6 (type 6 phosphodiesterase) from rod outer segments consists of two types of catalytic subunits, alpha and beta; two inhibitory gamma subunits; and one or more delta subunits found only on the soluble form of the enzyme. About 70% of
Sandra Osburn et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(3), 873-879 (2011-01-13)
The structure and reactivity of the cysteine methyl ester radical cation, CysOMe(.+) , have been examined in the gas phase using a combination of experiment and density functional theory (DFT) calculations. CysOMe(.+) undergoes rapid ion-molecule reactions with dimethyl disulfide, allyl
B E Svensson
The Biochemical journal, 253(2), 441-449 (1988-07-15)
Nine low-Mr thiols were compared with regard to their ability to function as myeloperoxidase-oxidase substrates under conditions where no auto-oxidation of the thiols could be observed. The methyl and ethyl esters of cysteine were found to be about twice as
Itai Chipinda et al.
Chemical research in toxicology, 19(3), 341-350 (2006-03-21)
Diisocyanates (dNCOs) are the most commonly reported cause of chemically induced occupational asthma, but the ultimate antigenic form is unknown. Reactions of the three most common monomeric dNCOs, hexamethylene dNCO (HDI), methylene diphenylisocyanate (MDI), and toluene dNCO (TDI), with cysteine

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