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Sigma-Aldrich

Hexaammineruthenium(III) chloride

98%

Synonym(s):

Hexaammineruthenium trichloride

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$54.60
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$151.00
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$487.00
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$4,020.00

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250 MG
$54.60
1 G
$151.00
5 G
$487.00
50 G
$4,020.00

About This Item

Linear Formula:
[Ru(NH3)6]Cl3
CAS Number:
14282-91-8
Molecular Weight:
309.61
EC Number:
238-176-8
MDL number:
MFCD00011478
UNSPSC Code:
12161600
PubChem Substance ID:
24855851
NACRES:
NA.22

$54.60

In StockDetails

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Quality Level

100

assay

98%

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

storage temp.

2-8°C

SMILES string

N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Ru+3]

InChI

1S/3ClH.6H3N.Ru/h3*1H;6*1H3;/q;;;;;;;;;+3/p-3

InChI key

GBDZMMXUOBAJMN-UHFFFAOYSA-K

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General description

Hexaammineruthenium III/II (HexRu(III)|HexRu(II)) couple is a commonly used electrochemical redox couple due to its chemical and electrochemical reversibility.[1]

Application

Hexaammineruthenium(III) chloride can be used as a precursor for the preparation of:
  • Ru/Al2O3 catalyst for CO2 hydrogenation.[2]
  • Bimetallic complexes ([Ru(NH3)6][Ag(CN)2]3·2H2O).[3]
  • Chloropentaammineruthenium(III) chloride.[4]
For small scale and high throughput uses, product is also available as ChemBeads (932183)

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW4274
MKCR6447
WXBD7993V
MKCS8077
WXBD7294V

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CO2 Hydrogenation over Ru/chi-Al2O3 Catalyst
Jeenjumras K, et al.
IOP Conference Series: Materials Science and Engineering, 311, 012023-012023 (2018)
Binuclear complexes of ruthenium ammines.
Creutz C and Taube H
Journal of the American Chemical Society, 95(4), 1086-1094 (1973)
Qian Yang et al.
Nanoscale, 9(46), 18523-18528 (2017-11-23)
A molecular check valve is a nanomachine that enables unidirectional molecular transport. In this work, we report a novel molecular check valve fabricated by asymmetric modification of a silica nanoporous membrane (SNM) consisting of parallel nanochannels with a diameter of
Leila Kashefi-Kheyrabadi et al.
Bioelectrochemistry (Amsterdam, Netherlands), 137, 107674-107674 (2020-09-20)
In the present study, a MoS2@Ti3C2Tx MXene hybrid-based electrochemical aptasensor (MEA) was introduced for sensitive and rapid quantification of Thyroxine (T4). T4 is a crucial hormone and plays a key role in various body functions. Therefore, there is high demand
Measurement of the diffusion coefficients of [Ru (NH3) 6] 3+ and [Ru (NH3) 6] 2+ in aqueous solution using microelectrode double potential step chronoamperometry.
Wang Y, et al,
Journal of Electroanalytical Chemistry, 652(1-2), 13-17 (2011)
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Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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