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重要文件

46125

Sigma-Aldrich

8-Ethoxy-N,N,N′,N′,N″,N″-hexamethylpyrene-1,3,6-trisulfonamide

suitable for fluorescence, ~85% (TLC)

同義詞:

8-Ethoxypyrene-1,3,6-tris(dimethylsulfonamide)

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About This Item

經驗公式(希爾表示法):
C24H29N3O7S3
CAS號碼:
分子量::
567.70
MDL號碼:
分類程式碼代碼:
12352200
PubChem物質ID:

化驗

~85% (TLC)

形狀

solid

溶解度

DMSO: soluble

螢光

λex 380 nm; λem 468 nm in DMSO
λex 380 nm; λem 520 nm (Reaction product)

適合性

suitable for fluorescence

SMILES 字串

CCOc1cc(c2ccc3c(cc(c4ccc1c2c34)S(=O)(=O)N(C)C)S(=O)(=O)N(C)C)S(=O)(=O)N(C)C

InChI

1S/C24H29N3O7S3/c1-8-34-19-13-20(35(28,29)25(2)3)16-11-12-18-22(37(32,33)27(6)7)14-21(36(30,31)26(4)5)17-10-9-15(19)23(16)24(17)18/h9-14H,8H2,1-7H3

InChI 密鑰

ZZBMLCMOOSUCTA-UHFFFAOYSA-N

應用

8-Ethoxy-N,N,N′,N′,N″,N″-hexamethylpyrene-1,3,6-trisulfonamide is an analog of 8-hydroxy-N,N,N′,N′,N″,N″-hexamethylpyrene-1,3,6-trisulfonamide (HPTA), a photoacid, used to investigate the steps involved in excited-state deprotonation in polar solvents using pump-probe spectroscopy and time correlated single photon counting fluorescence spectroscopy.

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

其他說明

Fluorogenic hydrolase substrate

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


分析證明 (COA)

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Observation of slow charge redistribution preceding excited-state proton transfer.
Spry DB, Fayer MD.
J. Chem. Phys. , 127, na-na (2007)
Charge redistribution and photoacidity: neutral versus cationic photoacids.
Spry DB, Fayer MD.
J. Chem. Phys. , 128, na-na (2008)
D B Spry et al.
The journal of physical chemistry. B, 113(30), 10210-10221 (2009-07-04)
Proton transfer in protonated Nafion fuel cell membranes is studied using several pyrene derivative photoacids. Proton transfer in the center of the Nafion nanoscopic water channels is probed with the highly charged photoacid 8-hydroxypyrene-1,3,6-trisulfonate (HPTS). At high hydration levels, both
E. Koller et al.
Appl. Fluoresc. Technol., 1, 15-15 (1989)

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