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Merck
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345695

Sigma-Aldrich

四氯化钛(IV) 溶液

1.0 M in toluene

同義詞:

四氯化钛

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About This Item

線性公式:
TiCl4
CAS號碼:
分子量::
189.68
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.55

形狀

liquid

反應適用性

reagent type: catalyst
core: titanium

濃度

0.95-1.10 M NaOH (titration)
1.0 M in toluene

密度

0.964 g/mL at 25 °C

SMILES 字串

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI 密鑰

XJDNKRIXUMDJCW-UHFFFAOYSA-J

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一般說明

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.

應用

TiCl4 can be used as a precursor for the synthesis of nanosized titaniuim dioxide.

訊號詞

Danger

危險分類

Acute Tox. 2 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

標靶器官

Central nervous system, Respiratory system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

46.4 °F - closed cup

閃點(°C)

8 °C - closed cup


分析證明 (COA)

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Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Yang Chen et al.
ChemSusChem, 4(10), 1498-1503 (2011-09-29)
Mesoporous TiO₂ beads with diameters of 320±50, 550±50, and 830±40 nm, comprising interconnected and densely packed TiO₂ nanocrystals, were used as working electrodes for dye-sensitized solar cells (DSCs). These electrodes possess high surface areas and superior light-scattering properties, which are ideal
Bratindranath Mukherjee et al.
Nanoscale, 5(1), 269-274 (2012-11-20)
The surface treatment of an anodized TiO(2) nanotube (T_NT) is very desirable for enhancing its photoelectrochemical properties and often is a prerequisite to deposition of any overlying layer for photoactivity efficiency improvement. This study provides a comparative analysis of the
Tian-Yi Ma et al.
Small (Weinheim an der Bergstrasse, Germany), 7(13), 1827-1837 (2011-05-17)
Ordered, hexagonal, mesoporous metal (Ti, Zr, V, Al)-phosphonate materials with microporous crystalline walls are synthesized through a microwave-assisted procedure by using triblock copolymer F127 as the template. Corresponding metal chlorides and ethylene diamine tetra(methylene phosphonic acid) are chosen as the

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