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Key Documents

31250

Sigma-Aldrich

铬酸钾

puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.5%

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About This Item

線性公式:
K2CrO4
CAS號碼:
分子量::
194.19
EC號碼:
MDL號碼:
分類程式碼代碼:
41116107
PubChem物質ID:

等級

ACS reagent
puriss. p.a.

agency

reag. Ph. Eur.

蒸汽密度

6.7 (vs air)

化驗

≥99.5%

雜質

≤0.005% in water insoluble matters

pH值

8.6-9.8 (20 °C, 5%)

mp

971 °C (lit.)

負離子痕跡

chloride (Cl-): ≤10 mg/kg
sulfate (SO42-): ≤50 mg/kg

正離子痕跡

Ca: ≤50 mg/kg
Fe: ≤20 mg/kg
Na: ≤200 mg/kg
Pb: ≤50 mg/kg

SMILES 字串

[K+].[K+].[O-][Cr]([O-])(=O)=O

InChI

1S/Cr.2K.4O/q;2*+1;;;2*-1

InChI 密鑰

XMXNVYPJWBTAHN-UHFFFAOYSA-N

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一般說明

Potassium chromate (K2CrO4) is the potassium salt having morphological features similar to potassium sulfate (isostructural). Its crystals exhibit rhombic crystal system. It can be manufactured by reacting potassium dichromate with potassium hydroxide. It has been reported to crystallize in orthorhombic space group. Production of potassium chromat by a new reaction system of KOH-KNO3-H2O (binary submolten salt system) has been proposed.

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Irrit. 2 - Muta. 1B - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Redetermination of the structures of potassium sulphate and potassium chromate: the effect of electrostatic crystal forces upon observed bond lengths.
McGinnety JA.
Acta Crystallographica Section B, Structural Science, 28(9), 2845-2852 (1972)
Comparative Study of Factors Influencing the Action of Corrosion Inhmitors for Mild Steel in Neutral Solution: II. Potassium Chromate.
Mercer AD and Jenkins IR.
British Corrosion Journal, 3(3), 130-135 (1968)
Eagleson M.
Concise Encyclopedia Chemistry, 881-881 (1994)
A new method of potassium chromate production from chromite and KOH-KNO3-H2O binary submolten salt system.
Sun Z, et al.
AIChE Journal, 55(10), 2646-2656 (2009)
Ying Li et al.
Colloids and surfaces. B, Biointerfaces, 65(1), 25-29 (2008-04-02)
Adsorption thermodynamic characteristic and kinetics of dissolved chromium from aqueous solutions onto humic acids (HAs) were studied. The results showed that the Freundlich isotherm model described the equilibrium data well. The negative DeltaG degrees confirmed the spontaneity of adsorption process.

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