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C1909

柠檬酸 一水合物

ACS reagent grade, ≥99.0%, powder

同義詞:

2-hydroxy-1,2,3-propanetricarboxylic acid monohydrate

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線性公式:
HOC(COOH)(CH2COOH)2 · H2O
CAS 編號:
分子量::
210.14
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
201-069-1
MDL number:
Beilstein/REAXYS Number:
4018641
Assay:
≥99.0%
Form:
powder
Grade:
ACS reagent
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產品名稱

柠檬酸 一水合物, ACS reagent, ≥99.0%

grade

ACS reagent

Quality Segment

assay

≥99.0%

form

powder

impurities

Substances carbonizable by hot sulfuric acid, passes test, ≤0.005% Insoluble matter

ign. residue

≤0.02%

pH

(1.8 at 50 g/l at 20 °C)

pKa 

(1) 3.13, (2) 4.76, (3) 6.4

solubility

H2O: soluble 54 % (w/w) at 10 °C (Citric acid in water), H2O: 59.2 % (w/w) at 20 °C (Citric acid in water), H2O: 84.0 % (w/w) at 100 °C (Citric acid in water)

anion traces

chloride (Cl-): ≤0.001%, oxalate (C2O42-): passes test (limit about 0.05%), phosphate (PO43-): ≤0.001%, sulfate (SO42-): ≤0.002%

cation traces

Fe: ≤3 ppm, Pb: ≤2 ppm

functional group

carboxylic acid

SMILES string

OC(CC(O)(C(O)=O)CC(O)=O)=O.O

InChI

1S/C6H8O7.H2O/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);1H2

InChI key

YASYEJJMZJALEJ-UHFFFAOYSA-N

General description

柠檬酸一水合物是一种有机酸。据报道,其水溶液的摩尔焓为ΔsolHm (298.15K, m = 0.0203molkg-1) = (29061±123)Jmol-1。它可以通过在柠檬酸合成期间在20-25°C下从柠檬酸溶液母液中结晶而制得。对其晶体生长动力学的研究表明,生长与尺寸呈线性相关。

一水柠檬酸是一种有机弱酸,在食品和饮料产品中用作天然防腐剂。

Application

使用柠檬酸一水合物制备的柠檬酸溶液可用于丙酮法 68Ga预纯化和放射性标记技术。[1]
柠檬酸一水合物可用作
  • 释放改良剂,用于改善熔体挤出Eudragit RS PO片剂中盐酸地尔硫卓的释放。[2]
  • 配制柠檬酸盐缓冲液,以便制备用于活体显微镜分析的血小板。[3]
  • 制备Tris-柠檬酸盐缓冲液,以用于细菌酶电泳。[4]

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本產品
33114C7129C0706
grade

ACS reagent

grade

ACS reagent, puriss. p.a.

grade

reagent grade

grade

-

assay

≥99.0%

assay

99.5-100.5% (calc. on anhydrous substance), 99.5-102%

assay

≥98% (GC/titration)

assay

≥99.5%

Quality Level

200

Quality Level

200

Quality Level

300

Quality Level

200

form

powder

form

solid

form

powder

form

powder

pH

(1.8 at 50 g/l at 20 °C)

pH

-

pH

-

pH

1.85 (25 °C, 50 g/L)

solubility

H2O: soluble 54 % (w/w) at 10 °C (Citric acid in water), H2O: 84.0 % (w/w) at 100 °C (Citric acid in water), H2O: 59.2 % (w/w) at 20 °C (Citric acid in water)

solubility

-

solubility

H2O: 100 mg/mL, clear, colorless (Turbidity)

solubility

H2O: 1 M, clear, colorless


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存儲類別/等級

11 - Combustible Solids

wgk

WGK 1

flash_point_f

345.0 °F - closed cup

flash_point_c

173.9 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. I need to prepare 100 ml of 1 molar citric acid solution. How do I prepare this and which product do I need to buy?

    1 answer
    1. The volume of 100 mL is equivalent to 0.1 Liters. And 1 molar (1 mole per liter) times 0.1 liters equals 0.1 moles. The molecular weight for Citric Acid Monohydrate is 210.14 grams per mole. And 0.1 moles times 210.14 grams per mole equals 21.0 grams. So to prepare the solution, dissolve 21.0 grams of citric acid monohydrate in about 75 mL of pure water, then bring the final volume to 100 mL. Citric Acid Monohydrate is very soluble in water.
      As far as which product to buy, many grades of citric acid and citric acid monohydrate are listed. Please contact your local Technical Service group and describe your intended application so that they can help you choose the appropriate grade.

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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