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Merck
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文件

90039

Supelco

Fenthion oxon sulfone-(S-methyl-d3)

PESTANAL®, analytical standard

同義詞:

Dimethyl 3-methyl-4-(methyl-d3-sulfonyl)phenyl phosphate, Fenoxon sulfone-(S-methyl-d3)

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About This Item

經驗公式(希爾表示法):
C10D3H12O6PS
分子量::
297.28
分類程式碼代碼:
41116107
PubChem物質ID:
NACRES:
NA.24

等級

analytical standard

品質等級

產品線

PESTANAL®

化驗

≥98.0% (HPLC)

儲存期限

limited shelf life, expiry date on the label

mp

40-46 °C

應用

agriculture

格式

neat

儲存溫度

2-8°C

SMILES 字串

O=P(OC)(OC)OC1=CC(C)=C(S(=O)(C([2H])([2H])[2H])=O)C=C1

相關類別

一般說明

Fenthion oxon sulfone-(S-methyl-d3) is a deuterated isotope analog of fenthion oxon sulfone-(S-methyl), a derivative of organophosphorus insecticide fenthion, wherein S-methyl protons are replaced by deuterium.

應用

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

法律資訊

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 2 Oral

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Simultaneous Analysis of Fenthion and Its Five Metabolites in Produce Using Ultra-High Performance Liquid Chromatography-Tandem Mass Spectrometry
Lee J and Kim J-H
Molecules (Basel), 25(8), 1938-1938 (2020)
Kuniyo Sugitate et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 28(7), 669-673 (2012-07-14)
Fenthion, fenthion sulfoxide, fenthion oxon sulfoxide and fensulfothion showed two different mass spectra in GC/MS, depending on their concentrations. The base peaks shifted to lower levels by 1 m/z at lower concentration, and no retention time shifts were observed.

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