推薦產品
等級
analytical standard
品質等級
產品線
PESTANAL®
化驗
≥98.0% (GC)
儲存期限
limited shelf life, expiry date on the label
應用
agriculture
格式
neat
儲存溫度
2-8°C
SMILES 字串
CN(C)CCCNC(OC([2H])([2H])C([2H])([2H])C([2H])([2H])[2H])=O
InChI
1S/C9H20N2O2/c1-4-8-13-9(12)10-6-5-7-11(2)3/h4-8H2,1-3H3,(H,10,12)/i1D3,4D2,8D2
InChI 密鑰
WZZLDXDUQPOXNW-GZAMCDGTSA-N
相關類別
一般說明
Propamocarb-(propyl-d7) is an isotope-labeled analog of systemic fungicide propamocarb, wherein propyl protons are substituted by deuterium.
應用
Propamocarb-(propyl-d7) may be used as a deuterated internal standard to quantify the pesticide analytes in foods of plant origin by two-dimensional liquid chromatography-tandem mass spectrometry (LC-MS/MS).
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.
Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.
法律資訊
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Warning
危險聲明
危險分類
Acute Tox. 4 Oral
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
Not applicable
閃點（°C）
Not applicable
Quick method for the analysis of numerous highly polar pesticides in foods of plant origin via LC-MS/MS involving simultaneous extraction with methanol (QuPPe-method)
Anastassiades M, et al.
EU Reference Laboratie for Residue of Pesticides, 9, 1-60 (2015)
Simultaneous determination of pesticides, mycotoxins, and metabolites as well as other contaminants in cereals by LC-LC-MS/MS
Kresse M, et al.
Journal of Chromatography. B, Biomedical Applications, 1117(2), 86-102 (2019)
Simultaneous determination of pesticides, mycotoxins, tropane alkaloids, growth regulators, and pyrrolizidine alkaloids in oats and whole wheat grains after online clean-up via two-dimensional liquid chromatography tandem mass spectrometry
Urban M, et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 54(2), 98-111 (2019)
Quick method for the analysis of numerous highly polar pesticides in foods of plant origin via LC-MS/MS involving simultaneous extraction with methanol (QuPPe-method)
Anastassiades M, et al.
Chemosphere, 1117(2), 86-102 (2019)
Dissipation kinetic studies of fenamidone and propamocarb in vegetables under greenhouse conditions using liquid and gas chromatography coupled to high-resolution mass spectrometry
Lopez-Ruiz R, et al.
EU Reference Laboratie for Residue of Pesticides, 226, 36-46 (2019)
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