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重要文件

58279

Sigma-Aldrich

靛红酸酐

technical, ≥94% (HPLC)

同義詞:

N-羧鄰胺苯甲酐, 衣托酸酐

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About This Item

經驗公式(希爾表示法):
C8H5NO3
CAS號碼:
分子量::
163.13
Beilstein:
136786
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:

蒸汽密度

5.6 (vs air)

等級

technical

化驗

≥94% (HPLC)

mp

233 °C (dec.) (lit.)

SMILES 字串

O=C1Nc2ccccc2C(=O)O1

InChI

1S/C8H5NO3/c10-7-5-3-1-2-4-6(5)9-8(11)12-7/h1-4H,(H,9,11)

InChI 密鑰

TXJUTRJFNRYTHH-UHFFFAOYSA-N

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其他說明

综述;用于 2-氨基苯甲酰化的试剂。

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分析證明 (COA)

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G.M. Coppola
Synthesis, 505-505 (1980)
M.C. Venuti
Synthesis, 266-266 (1982)
Zheng-Hui Guan et al.
Journal of the American Chemical Society, 134(42), 17490-17493 (2012-10-12)
A Pd-catalyzed regioselective C-H bond carbonylation of N-alkyl anilines for the synthesis of isatoic anhydrides has been developed. The key Pd-catalyst intermediate has been isolated and characterized. This novel Pd-catalyzed carbonylation reaction tolerates a wide range of functional groups and
K Siva Kumar et al.
Organic & biomolecular chemistry, 10(15), 3098-3103 (2012-03-10)
A one-pot cascade reaction has been developed leading to the concurrent construction of six and five membered fused N-heterocyclic rings of indazolo[3,2-b]quinazolinones. The methodology involved the reaction of isatoic anhydride, a hydrazine and o-iodo benzaldehyde in the presence of Pd(PPh(3))(4)
Asha M D'Souza et al.
Organic letters, 13(3), 486-489 (2010-12-24)
A nonstabilized azomethine ylide reacts with a wide range of substituted isatoic anhydrides to afford novel 1,3-benzodiazepin-5-one derivatives, which are generally isolated in high yield. The transformations involve 1,3-dipolar cycloaddition reactions of the ylide with the anhydrides to give transient

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