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文件

46430

Sigma-Aldrich

邻氟苯乙酮

purum, ≥97.0% (GC)

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About This Item

線性公式:
FC6H4COCH3
CAS號碼:
445-27-2
分子量：:
138.14
Beilstein:
2041344
EC號碼:
207-156-0
MDL號碼:
MFCD00000320
分類程式碼代碼:
12352100
PubChem物質ID:
24870161

等級

purum

化驗

≥97.0% (GC)

折射率

n20/D 1.507 (lit.)
n20/D 1.509

bp

187-189 °C (lit.)

密度

1.137 g/mL at 20 °C (lit.)

SMILES 字串

CC(=O)c1ccccc1F

InChI

1S/C8H7FO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3

InChI 密鑰

QMATYTFXDIWACW-UHFFFAOYSA-N

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應用

2′-Fluoroacetophenone may be used as starting reagent in the synthesis of ascididemin.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319

防範說明

P305 + P351 + P338

危險分類

Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

143.6 °F - closed cup

閃點（°C）

62 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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分析證明 (COA)

Lot/Batch Number
438208/1
429299/1
374327/1
341827/1

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Ida Nymann Petersen et al.
Chemical communications (Cambridge, England), 48(72), 9092-9094 (2012-08-07)
A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended
The enantioselective reduction of 2'-fluoroacetophenone utilizing a simplified CBS-reduction procedure.
Garrett CE, et al.
Tetrahedron Asymmetry, 13(13), 1347-1349 (2002)

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