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Merck
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文件

1.02487

Sigma-Aldrich

六水合三氯化铬(III) 六水合物

Technipur®

同義詞:

三氯化铬六水合物, 六水氯化无色铵

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About This Item

線性公式:
CrCl3 · 6H2O
CAS號碼:
分子量::
266.45
MDL號碼:
分類程式碼代碼:
12352302
NACRES:
NA.21

品質等級

pH值

2.4-2.6 (20 °C, 50-53 g/L in H2O)

mp

81 °C

密度

1.76 g/mL at 25 °C (lit.)

SMILES 字串

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Cr](Cl)Cl

InChI

1S/3ClH.Cr.6H2O/h3*1H;;6*1H2/q;;;+3;;;;;;/p-3

InChI 密鑰

LJAOOBNHPFKCDR-UHFFFAOYSA-K

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應用

Chromium(III) chloride hexahydrate can be used as a:
  • Source of Cr(II) in the Takai reaction.
  • Component of the deep eutectic solvent applicable as a catalyst in the esterification of carboxylic acids with alcohols.
  • Precursor to prepare metal-oxide-doped amorphous titanium oxides, which are used as catalysts in the oxidative dehydrogenation of ethylbenzene.

法律資訊

Technipur is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Warning

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Met. Corr. 1 - Skin Sens. 1B

儲存類別代碼

8B - Non-combustible, corrosive hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

does not flash

閃點(°C)

does not flash


分析證明 (COA)

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Deep eutectic solvent choline chloride?2CrCl3?6H2O: an efficient catalyst for esterification of formic and acetic acid at room temperature
Cao J, et al.
Royal Society of Chemistry Advances, 6, 21612-21616 (2016)
Amorphous porous MxTi mixed oxides as catalysts for the oxidative dehydrogenation of ethylbenzene
Li WY, et al.
Catalysis Letters, 69, 181?188 -181?188 (2000)
An Alternative Procedure in the Takai Reaction Using Chromium(III) Chloride Hexahydrate as a Convenient Source of Chromium(II)
Auge J, et al.
Synthetic Communications, 33(21) (2003)

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