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Merck
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重要文件

915556

Sigma-Aldrich

HNMB

≥98%

同義詞:

4-[(E)-[(2-hydroxy-1-naphthalenyl)methylene]amino]-3-methyl benzoic acid, Aggregation-induced emmision (AIE) materials, Mechanochromic luminescent (MCL) materials

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About This Item

經驗公式(希爾表示法):
C19H15NO3
CAS號碼:
分子量::
305.33
MDL號碼:
分類程式碼代碼:
12352103
NACRES:
NA.23

品質等級

化驗

≥98%

形狀

solid

顏色

white

mp

292.9 °C

紫外吸收

λ: 317 nm Amax
λ: 443 nm Amax

SMILES 字串

N(=C\c2c3c(ccc2O)cccc3)/c1c(cc(cc1)C(=O)O)C

InChI

1S/C19H15NO3/c1-12-10-14(19(22)23)6-8-17(12)20-11-16-15-5-3-2-4-13(15)7-9-18(16)21/h2-11,21H,1H3,(H,22,23)/b20-11+

InChI 密鑰

HCGGUBXKKWXERU-RGVLZGJSSA-N

應用

HNMB is a mechanochromic luminescent material with aggregation-induced emission (AIE). It has applications for pressure sensing and mapping.
In biology, pressure could direct the folding-unfolding of protein molecules, guide blood stream and even control the cell migration. The complexity with these cases makes the monitor and measurement of pressure from conventional force sensor based on classical mechanics impractical. Based on mechanical sensitive materials with ingenious design at the molecular level, a new way to detect pressure is developed. And mechanochromic luminescent (MCL) materials have formed a vital part of such materials. They are intentionally endowed with the ability to change luminescence property (e.g., emission wavelength, emission intensity and lifetime) under mechanical force, which can be readily detected by naked eyes or instruments. As molecule-based sensors, they are compatible to various flexible substrates and arbitrarily curvilinear surfaces, facilitating many applications.

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Eethamukkala Ubba et al.
Chemistry, an Asian journal, 13(21), 3106-3121 (2018-08-10)
Mechanoluminescence (ML) involves the emission of light from various organic and inorganic materials upon mechanical stimulus. In this review, we contemplate the advances of metal-free, purely organic ML compounds with aggregation-induced emission (AIE), which give strong emission upon mechanical force.
Trap-controlled mechanoluminescent materials.
Zhang J C, et al.
Progress in Materials Science, 103, 678-742 (2019)
Xin Qian et al.
Advanced materials (Deerfield Beach, Fla.), 30(25), e1800291-e1800291 (2018-05-04)
Mechanically driven light generation is an exciting and under-exploited phenomenon with a variety of possible practical applications. However, the current driving mode of mechanoluminescence (ML) devices needs strong stimuli. Here, a flexible sensitive ML device via nanodopant elasticity modulus modification
Mengyao Zhang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 220, 117125-117125 (2019-05-29)
In this study, we report a new compound, (E)-4-(((2-hydroxynaphthalen-1-yl)methylene)amino)-3-methylbenzoic acid (HNMB), which shows aggregation-induced emission property as well as intramolecular charge transfer (ICT) nature. In addition, it exhibits unique mechanochromic luminescence (MCL). The HNMB solid powder emits strong emission but

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