跳轉至內容
Merck
全部照片(1)

文件

900624

Sigma-Aldrich

Di-t-butyl oxaziridine

≥95%

同義詞:

Kurti oxaziridine

登入查看組織和合約定價


About This Item

經驗公式(希爾表示法):
C9H19NO
CAS號碼:
分子量::
157.25
分類程式碼代碼:
12352000
NACRES:
NA.22

品質等級

化驗

≥95%

形狀

liquid

存貨情形

available only in USA

折射率

n/D 1.4453

密度

0.90 g/mL

儲存溫度

2-8°C

SMILES 字串

CC(C)(C)C1(NO1)C(C)(C)C

應用

This oxaziridine has been used in synthetic methods for amination, heteroatom transfer, and C-H functionalization. Recently, the lab of Laszlo Kurti demonstrated its application for direct electrophilic primary and secondary amination of arylmetals in the presence of Cu(I) salts -- void of precious metal catalysts, ligands, protecting groups, or directing groups.

象形圖

Flame

訊號詞

Danger

危險聲明

危險分類

Self-react. C

儲存類別代碼

5.2 - Organic peroxides and self-reacting hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

143.6 °F

閃點(°C)

62 °C


分析證明 (COA)

輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號,寫有 ‘Lot’或‘Batch’.。

已經擁有該產品?

您可以在文件庫中找到最近購買的產品相關文件。

存取文件庫

Zhe Zhou et al.
Journal of the American Chemical Society, 139(1), 115-118 (2016-12-23)
Herein we disclose a novel method for the facile transfer of primary (-NH2) and secondary amino groups (-NHR) to heteroaryl- as well as arylcuprates at low temperature without the need for precious metal catalysts, ligands, excess reagents, protecting and/or directing
Yan Xu et al.
Nature chemistry, 7(10), 829-834 (2015-09-24)
Site-selective C-H functionalization has emerged as an attractive tool for derivatizing complex synthetic intermediates, but its use for late-stage diversification is limited by the functional groups that can be introduced, especially at unactivated sp(3)-hybridized positions. To overcome this, we introduce
Hongyin Gao et al.
Nature chemistry, 9(7), 681-688 (2017-06-24)
Arylmetals are highly valuable carbon nucleophiles that are readily and inexpensively prepared from aryl halides or arenes and widely used on both laboratory and industrial scales to react directly with a wide range of electrophiles. Although C-C bond formation has
Synthesis of Alkoxylamines by Alkoxide Amination with 3,3'-Di-tert-butyloxaziridine.
Ingrid C. Choong et al.
The Journal of organic chemistry, 64(18), 6528-6529 (2001-10-25)

相關內容

Amines and their derivatives are ubiquitous substances since they make up the overwhelming majority of drug molecules, agrochemicals as well as many compounds that are produced by plants and living organisms (i.e., natural products).

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

聯絡技術服務