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88508

Sigma-Aldrich

二[三(3-(十七氟辛基)苯基)膦]二氯化钯(II)

≥95% (31P-NMR)

同義詞:

二[三(3-(全氟辛基)苯基)膦]二氯化钯(II)

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About This Item

經驗公式(希爾表示法):
C84H24Cl2F102P2Pd
CAS號碼:
分子量::
3210.20
MDL號碼:
分類程式碼代碼:
12352200
PubChem物質ID:

化驗

≥95% (31P-NMR)

SMILES 字串

Cl[Pd]Cl.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)c1cccc(c1)P(c2cccc(c2)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c3cccc(c3)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)c4cccc(c4)P(c5cccc(c5)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)c6cccc(c6)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F

應用

氟两相体系 (FBS) 中的 Stille 和 Suzuki 偶联反应催化剂

其他說明

全氟标记 Pd 络合物,可作为氟两相体系中 Stille 偶联反应、 钯催化 Suzuki 偶联反应的催化剂。

分析證明 (COA)

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T. Osswald et al.
Tetrahedron Letters, 42, 2965-2965 (2001)
S. Schneider et al.
Angewandte Chemie (International Edition in English), 112, 4293-4293 (2000)
S. Schneider et al.
Helvetica Chimica Acta, 84, 735-735 (2001)

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