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Merck
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重要文件

797294

Sigma-Aldrich

1,1,2,3,4,5-六苯基-1H-噻咯

同義詞:

1,1,2,3,4,5-六苯基甲硅烷基, 1,1,2,3,4,5-六苯基硅杂环戊-2,4-二烯, 1,1,2,3,4,5-六苯基硅杂环戊二烯, HPS, 六苯基硅杂环戊-2,4-二烯, 六苯基硅环戊二烯

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About This Item

經驗公式(希爾表示法):
C40H30Si
CAS號碼:
分子量::
538.75
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

化驗

98%

形狀

solid

mp

188-193 °C

SMILES 字串

C1(C2=CC=CC=C2)=C(C3=CC=CC=C3)C(C4=CC=CC=C4)=C(C5=CC=CC=C5)[Si]1(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/C40H30Si/c1-7-19-31(20-8-1)37-38(32-21-9-2-10-22-32)40(34-25-13-4-14-26-34)41(35-27-15-5-16-28-35,36-29-17-6-18-30-36)39(37)33-23-11-3-12-24-33/h1-30H

InChI 密鑰

QAKMXYFDVPDIPT-UHFFFAOYSA-N

一般說明

HPS 是用于 OLED 发射层的聚集诱导发射(AIE)材料。1,4,5,6,7,7-六苯基-7-硅双环[2.2.1]庚-5-烯-2,3-二羧酸酐(XIb)的光解和热解可能导致六苯基硅环戊二烯的形成。

應用

六苯基硅烷基环戊二烯可与丙烯酸乙酯进行 π4s+π2s 环加成反应,形成双环硅亚庚烯。同一项研究报道了与各种亲双烯体类似的环加成反应。六苯基硅环戊二烯与过苯甲酸的反应生成四苯基呋喃和顺二苯甲酰二苯乙烯。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Photochemical and thermal transformations of 7-silabicyclo[2.2.1]Heptadiene and 7-silabicyclo[2.2.1]heptene systems
Balasubramanian R and George MV
Journal of Organometallic Chemistry null
Synthesis, Light Emission, Nanoaggregation, and Restricted Intramolecular Rotation of 1,1-Substituted 2,3,4,5-Tetraphenylsiloles
Junwu Chen, Charles C. W. Law, Jacky W. Y. Lam, et al
Chemistry of Materials, 15(7), 1535-1546 (2003)
Peracid oxidation and photooxygenation reactions of silacyclopentadienes,
Mahajan MP, et al.
Tetrahedron null
Symmetry allowed ?4s+?2s additions silacyclopentadienes
Balasubramanian R and George MV
Tetrahedron null
Symmetry allowed ?4s+?2s additions silacyclopentadienes
Balasubramanian R and George MV
Tetrahedron, 2395-2404 null

文章

AIE Luminogens - Family of new materials with multifaceted functionalities. Find some representative applications of the AIEgens

Organic Light-emitting Diodes (OLEDs) are solid-state devices that transform electrical energy into light. OLEDs are considered the next generation technology for high-resolution flexible displays and solid state lighting, attracting intense scientific and industrial interest.

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