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重要文件

790796

Sigma-Aldrich

Zinc benzylsulfinate

同義詞:

Zinc benzylsulfinate, Baran BNS Reagent

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About This Item

經驗公式(希爾表示法):
C14H14O4S2Zn
CAS號碼:
分子量::
375.78
分類程式碼代碼:
12352002
PubChem物質ID:
NACRES:
NA.22

形狀

solid

反應適用性

reaction type: Alkylations
reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

reagent type: diversification reagent

mp

56 °C (Decomposition)

儲存溫度

2-8°C

SMILES 字串

O=S(O[Zn]OS(CC1=CC=CC=C1)=O)CC2=CC=CC=C2

InChI

1S/2C7H8O2S.Zn/c2*8-10(9)6-7-4-2-1-3-5-7;/h2*1-5H,6H2,(H,8,9);/q;;+2/p-2

InChI 密鑰

AHSIXHPQMGLVIG-UHFFFAOYSA-L

應用

Zinc benzylsulfinate (BNS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

其他說明

may contain up to 1 mole eq ZnCl2

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

Lot/Batch Number

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Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified
Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry

文章

Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

在資源和時間有限的情況下,針對化學產業的需求,快速開發出多樣化的 (雜) 芳香族支架,確保效率。

我們的科學家團隊在所有研究領域都有豐富的經驗,包括生命科學、材料科學、化學合成、色譜、分析等.

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