化驗
≥95.0% (HPLC)
95.0-105.0% (NT)
形狀
powder
光學純度
enantiomeric excess: ≥98.0%
SMILES 字串
N[C@H]1[C@H](N)[C@H]2c3ccccc3[C@@H]1c4ccccc24
InChI
1S/C16H16N2/c17-15-13-9-5-1-2-6-10(9)14(16(15)18)12-8-4-3-7-11(12)13/h1-8,13-16H,17-18H2/t13-,14+,15-,16-/m1/s1
InChI 密鑰
NWDYSRZJOLDMRE-QKPAOTATSA-N
應用
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:
- To synthesize pyridine based C2-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
- To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
- To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.
包裝
Bottomless glass bottle. Contents are inside inserted fused cone.
儲存類別代碼
13 - Non Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
A heterobimetallic Ga/Yb-Schiff base complex for catalytic asymmetric α-addition of isocyanides to aldehydes
Journal of the American Chemical Society, 131(24), 8384-8385 (2009)
Periphery-functionalized porous organic cages
Chemistry?A European Journal , 22(46), 16547-16553 (2016)
A method for the synthesis of pyridine-based C2-symmetrical chiral nucleophilic organocatalysts via Pd-catalyzed coupling
Tetrahedron Asymmetry, 23(24), 1694-1699 (2012)
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