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Merck
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763071

Sigma-Aldrich

3,5-双（2-十二烷基硫代羰基硫代硫基硫代-1-氧代丙氧基）苯甲酸

98% (HPLC)

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About This Item

經驗公式（希爾表示法）:
C39H62O6S6
分子量：:
819.30
MDL號碼:
MFCD22666443
分類程式碼代碼:
12352100
PubChem物質ID:
329767026
NACRES:
NA.23

化驗

98% (HPLC)

形狀

powder or crystals

mp

60-65 °C

儲存溫度

2-8°C

SMILES 字串

CCCCCCCCCCCCSC(=S)SC(C)C(=O)Oc1cc(OC(=O)C(C)SC(=S)SCCCCCCCCCCCC)cc(c1)C(O)=O

InChI

1S/C39H62O6S6/c1-5-7-9-11-13-15-17-19-21-23-25-48-38(46)50-30(3)36(42)44-33-27-32(35(40)41)28-34(29-33)45-37(43)31(4)51-39(47)49-26-24-22-20-18-16-14-12-10-8-6-2/h27-31H,5-26H2,1-4H3,(H,40,41)

InChI 密鑰

GOLRGLNMILBFFI-UHFFFAOYSA-N

一般說明

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.
Reversible addition-fragmentation chain transfer (RAFT) polymerization is used to produce narrow polydispersity polymers of complex architecture. 3,5-Bis(2-dodecylthiocarbonothioylthio-1-oxopropoxy)benzoic acid is a carboxylic acid functionalised trithiocarbonate RAFT agent. It is used to form well-defined block copolymers. They have good control of polymerisation for a wide range of vinyl monomers.

應用

Used in the synthesis of macro-Chain Transfer Agent (CTA) which are used in the RAFT polymerisation of vinylic monomers like styrene, acrylate and acrylamide.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析證明 (COA)

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Block copolymers of poly (2-oxazoline) s and poly (meth) acrylates: a crossover between cationic ring-opening polymerization (CROP) and reversible addition-fragmentation chain transfer (RAFT).
Krieg, A., Weber, C., Hoogenboom, R., Becer, C. R., & Schubert, U. S.
ACS Macro Letters, 1(6), 776-779 (2012)
Thiocarbonylthio compounds (SC (Z) SR) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization).
Chiefari, J., Mayadunne, R. T., Moad, C. L., Moad, G., Rizzardo, E., Postma, A., & Thang, S. H.
Macromolecules, 36(7), 2273-2283 (2003)
One-step synthesis of block copolymers using a hydroxyl-functionalized trithiocarbonate RAFT agent as a dual initiator for RAFT polymerization and ROP
Kang, H. U., Yu, Y. C., Shin, S. J., & Youk, J. H.
Journal of Polymer Science Part A: Polymer Chemistry, 51(4), 774-779 (2013)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

文章

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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