化驗
95%
折射率
n20/D 1.496
密度
0.917 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
CC(C)[SiH](C(C)C)c1ccccn1
InChI
1S/C11H19NSi/c1-9(2)13(10(3)4)11-7-5-6-8-12-11/h5-10,13H,1-4H3
InChI 密鑰
XPUAXJBYLPPFKA-UHFFFAOYSA-N
應用
Reagent commonly used in acyloxylation reactions
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
183.9 °F
閃點（°C）
84.4 °C
The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes
Huang, C.; et al.
Advanced Synthesis & Catalysis, 353, 1285-1305 (2011)
Natalia Chernyak et al.
Journal of the American Chemical Society, 132(24), 8270-8272 (2010-06-01)
A new general and easily installable silicon-tethered pyridyl-containing directing group (PyDipSi) that allows for highly efficient and regioselective Pd-catalyzed ortho C-H acyloxylation of arenes has been developed. It has also been demonstrated that this directing group can efficiently be removed
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