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描述
Band gap: 1.8 eV
形狀
powder
分子量
average Mn 7,000-35,000 by GPC
λmax
670 nm (thin film)
軌道能量
HOMO -5.6 eV
LUMO -3.8 eV
半導體屬性
P-type (mobility=1.0 x 10-4 cm2/V·s) (OFET)
一般說明
HOMO: -5.6 eV
LUMO: -3.8 eV
UV absorption: λmax = 670 nm; Eg = 1.73 eV
Solubility: This polymer can be dissolved easily in chloroform, chlorobenzene, dichlorobenzene
LUMO: -3.8 eV
UV absorption: λmax = 670 nm; Eg = 1.73 eV
Solubility: This polymer can be dissolved easily in chloroform, chlorobenzene, dichlorobenzene
應用
High-Efficiency Organic Solar Cells (OPVs)
Power conversion efficiency (PCE): 7.3%
Open circuit voltage (Voc): 0.88 V
Short circuit current density (Jsc): 12.2 mA/cm2
Fill factor (FF): 0.69
Power conversion efficiency (PCE): 7.3%
Open circuit voltage (Voc): 0.88 V
Short circuit current density (Jsc): 12.2 mA/cm2
Fill factor (FF): 0.69
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
Ta-Ya Chu et al.
Journal of the American Chemical Society, 133(12), 4250-4253 (2011-03-08)
A new alternating copolymer of dithienosilole and thienopyrrole-4,6-dione (PDTSTPD) possesses both a low optical bandgap (1.73 eV) and a deep highest occupied molecular orbital energy level (5.57 eV). The introduction of branched alkyl chains to the dithienosilole unit was found
Xugang Guo et al.
Journal of the American Chemical Society, 134(44), 18427-18439 (2012-10-04)
Rational creation of polymeric semiconductors from novel building blocks is critical to polymer solar cell (PSC) development. We report a new series of bithiopheneimide-based donor-acceptor copolymers for bulk-heterojunction (BHJ) PSCs. The bithiopheneimide electron-deficiency compresses polymer bandgaps and lowers the HOMOs--essential
文章
Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.
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