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Merck
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重要文件

745928

Sigma-Aldrich

PDTSTPD

同義詞:

Poly[(5,6-dihydro-5-octyl-4,6-dioxo-4H-thieno[3,4-c]pyrrole-1,3-diyl)[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b′;]dithiophene-2,6-diyl]]

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About This Item

線性公式:
(C38H53NO2S3Si)n
CAS號碼:
分類程式碼代碼:
12352103

描述

Band gap: 1.8 eV

形狀

powder

分子量

average Mn 7,000-35,000 by GPC

λmax

670 nm (thin film)

軌道能量

HOMO -5.6 eV 
LUMO -3.8 eV 

半導體屬性

P-type (mobility=1.0 x 10-4 cm2/V·s) (OFET)

一般說明

HOMO: -5.6 eV
LUMO: -3.8 eV
UV absorption: λmax = 670 nm; Eg = 1.73 eV
Solubility: This polymer can be dissolved easily in chloroform, chlorobenzene, dichlorobenzene

應用

High-Efficiency Organic Solar Cells (OPVs)
Power conversion efficiency (PCE): 7.3%
Open circuit voltage (Voc): 0.88 V
Short circuit current density (Jsc): 12.2 mA/cm2
Fill factor (FF): 0.69

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Ta-Ya Chu et al.
Journal of the American Chemical Society, 133(12), 4250-4253 (2011-03-08)
A new alternating copolymer of dithienosilole and thienopyrrole-4,6-dione (PDTSTPD) possesses both a low optical bandgap (1.73 eV) and a deep highest occupied molecular orbital energy level (5.57 eV). The introduction of branched alkyl chains to the dithienosilole unit was found
Xugang Guo et al.
Journal of the American Chemical Society, 134(44), 18427-18439 (2012-10-04)
Rational creation of polymeric semiconductors from novel building blocks is critical to polymer solar cell (PSC) development. We report a new series of bithiopheneimide-based donor-acceptor copolymers for bulk-heterojunction (BHJ) PSCs. The bithiopheneimide electron-deficiency compresses polymer bandgaps and lowers the HOMOs--essential

文章

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

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