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Merck
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744441

Sigma-Aldrich

5-Chloro-5H-dibenzo[a,d]cycloheptene

97%

同義詞:

5H-Dibenzo[a,d]cyclohepten-5-yl chloride, Dibenzosuberenyl chloride, tropCl

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About This Item

經驗公式(希爾表示法):
C15H11Cl
CAS號碼:
分子量::
226.70
Beilstein:
515093
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:

化驗

≥96.5% (HPLC)
97%

形狀

powder

SMILES 字串

ClC1C(C=CC=C2)=C2C=CC3=C1C=CC=C3

InChI

1S/C15H11Cl/c16-15-13-7-3-1-5-11(13)9-10-12-6-2-4-8-14(12)15/h1-10,15H

InChI 密鑰

XUDMFUCJNFYMRZ-UHFFFAOYSA-N

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

象形圖

Environment

訊號詞

Warning

危險聲明

防範說明

危險分類

Aquatic Acute 1 - Aquatic Chronic 1

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Ethanol as hydrogen donor: highly efficient transfer hydrogenations with rhodium(I) amides.
Theo Zweifel et al.
Angewandte Chemie (International ed. in English), 47(17), 3245-3249 (2008-03-19)
Torsten Büttner et al.
Chemical communications (Cambridge, England), 24(24), 2820-2821 (2004-12-16)
A combination of the rigid bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine (trop(2)NH) and 5-amino-5H-dibenzo[a,d]cycloheptene (tropNH(2)) ligand allowed the synthesis of the stable pentacoordinated 18 electron amine olefin rhodium(i) complex [Rh(trop(2)NH)(tropNH(2))]O(3)SCF(3)(); this complex can be cleanly deprotonated [pK(a)(DMSO) = 20.6(1)] to the corresponding amide [Rh(trop(2)N)(tropNH(2))](6) which
Chiral Rhodium(I) and Iridium(I) Amino-Olefin Complexes:? pKa, N-H Bond Dissociation Energy, and Catalytic Transfer Hydrogenation
Maire, P., et al.
Organometallics, 24, 3207-3218 (2005)
Electromeric rhodium radical complexes.
Florian Frank Puschmann et al.
Angewandte Chemie (International ed. in English), 49(2), 385-389 (2009-12-04)
Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines
Zweifel, T., et al.
Angewandte Chemie (International Edition in English), 49, 559-563 (2009)

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