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Merck
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文件

743003

Sigma-Aldrich

2-过氧化丁酮

technical

同義詞:

甲基乙基酮过氧化物, 过氧化甲乙酮

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About This Item

線性公式:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
CAS號碼:
分子量::
210.22
Beilstein:
1759757
MDL號碼:
分類程式碼代碼:
12352120
PubChem物質ID:
NACRES:
NA.22

等級

technical

形狀

liquid

包含

2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer

反應適用性

reagent type: oxidant

折射率

n20/D 1.432

密度

1.053 g/mL at 20 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI 密鑰

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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應用

反应物用于:
  • 过氧化甲乙酮绝热失控反应的研究
  • 磨料溶出方波伏安法测定考古玻璃中的金属离子
  • 过氧化氢和过氧化氢清除物质的光子发射成像
  • 亚磷酰胺法合成寡核苷酸
  • 核苷亚磷酸酯氧化成磷酸盐
  • 人血浆谷胱甘肽过氧化物酶作为氢过氧化物酶还原催化剂的比较

乙醇-水体系中固定化血红蛋白直接电化学催化的分析物

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B

儲存類別代碼

5.2 - Organic peroxides and self-reacting hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

132.8 °F - closed cup

閃點(°C)

56 °C - closed cup


分析證明 (COA)

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Oesophageal stenosis in a child caused by ingestion of methyl ethyl ketone peroxide.
A Prez-Martnez et al.
European journal of pediatrics, 156(12), 976-977 (1998-02-07)
P J Karhunen et al.
Human & experimental toxicology, 9(3), 197-200 (1990-05-01)
Fatal massive peripheral zonal hepatic necrosis developed in a 47-year-old man who accidentally ingested a solution of methyl ethyl ketone peroxide (MEKP) in dimethyl phthalate. Such solutions contain about 10% active oxygen. The clinical course was characterized by temporary cardiac
M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and

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