推薦產品
形狀
liquid
反應適用性
core: manganese
reagent type: catalyst
濃度
0.5 M in THF
密度
0.956 g/mL at 25 °C
SMILES 字串
[Li+].[Li+].Cl[Mn--](Cl)(Cl)Cl
InChI
1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4
InChI 密鑰
VJOUQNFWQPCDPE-UHFFFAOYSA-J
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應用
Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant
Reactant for:
Reagent for the preparation of Rieke manganese
Reactant for:
- Transmetalation reactions
- Nickel-imidazolium carbene-catalyzed coupling reactions
Reagent for the preparation of Rieke manganese
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
1.4 °F - closed cup
閃點（°C）
-17.0 °C - closed cup
分析證明 (COA)
輸入產品批次/批號來搜索 分析證明 (COA)。在產品’s標籤上找到批次和批號，寫有 ‘Lot’或‘Batch’.。
A. Leleu, et al.,
Advanced Synthesis & Catalysis, 348, 1086-1092 (2006)
José M Concellón et al.
The Journal of organic chemistry, 72(21), 7974-7979 (2007-09-25)
A complete E-selective synthesis of alpha,beta-unsaturated amides through a sequential reaction of a range of dichloroamides with a variety of aldehydes promoted by Rieke manganese (Mn*) is reported. A mechanism based on a sequential aldol-type reaction and a completely stereoselective
Manganese- or iron-catalyzed homocoupling of grignard reagents using atmospheric oxygen as an oxidant.
Gérard Cahiez et al.
Journal of the American Chemical Society, 129(45), 13788-13789 (2007-10-20)
A. Eloi, et al.,
Organometallics, 28, 925-928 (2009)
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