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Merck
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674133

Sigma-Aldrich

包封于氢氧化铝基体内的钯纳米粒子

0.5 wt. % loading

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About This Item

線性公式:
Pd/AlO(OH)
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

形狀

solid

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

SMILES 字串

[Pd].O[Al]=O

InChI

1S/Al.H2O.O.Pd/h;1H2;;/q+1;;;/p-1

InChI 密鑰

BBEPUHUDSUQPRM-UHFFFAOYSA-M

相關類別

一般說明

非均相强效钯催化剂。

應用

Catalyst for:
  • Solvent-free hydrogenation
  • Aerobic alcohol oxidation
可回收纳米催化剂,用于伯胺的外消旋作用。与脂肪酶共同使用,通过动态动力学拆分生成对映纯胺。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Organic letters, 9(6), 1157-1159 (2007-02-13)
A practical procedure for the dynamic kinetic resolution (DKR) of primary amines has been developed. This procedure employs a palladium nanocatalyst as the racemization catalyst, a commercial lipase (Novozym-435) as the resolution catalyst, and ethyl acetate or ethyl methoxyacetate as

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