656577

1,3-二异丙基咪唑氯

97%

• 同義詞: N,N′-(异丙基)氯化咪唑鎓
• 經驗公式（希爾表示法）: C₉H₁₇ClN₂
• CAS號碼: 139143-09-2
• 分子量：: 188.70
• MDL號碼: MFCD03840577
• 分類程式碼代碼: 12352005
• PubChem物質ID: 24884209
• NACRES: NA.22

屬性

• 化驗: 97%
• 形狀: solid
• 反應適用性: reagent type: catalyst
• 環保替代產品特色: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 182-186 °C
• 環保替代類別: Aligned,
• SMILES 字串: [Cl-].CC(C)n1cc[n+](c1)C(C)C
• InChI: 1S/C9H17N2.ClH/c1-8(2)10-5-6-11(7-10)9(3)4;/h5-9H,1-4H3;1H/q+1;/p-1
• InChI 密鑰: DOFXKPAOJLLPII-UHFFFAOYSA-M

描述

一般說明

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

應用

1,3-Diisopropylimidazolium chloride may be used to prepare:

• 1,3-Diisopropylimidazole-2-thione by reacting with sulfur in the presence of potassium carbonate.
• (C₉H₇)NiCl(1,3-diisopropylimidazol-2- ylidene) by reacting with bis-indenyl nickel-(II).
• Ruthenium N-heterocyclic carbene complexes, which are efficient catalysts for the amidation of primary alcohols and amines.

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

安全資訊

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves